类Fenton反应对偶氮染料橙黄II的脱色研究——1.pdfVIP

7 2 Vol. 7, No. 2 2 0 0 6 2 Techn iques and Equ ipm ent for Environm ental Pollution Control Fe . 2 0 0 6 Fenton II * 张道斌 张 晖 曾志武 李 闯 (, 430079) II, FeNTA /H O Fenton 2 2 : [H O ] = 20 mm ol/L, [ FeNTA] = 25 mm ol/L, pH = 3 pH H O FeNTA 2 2 2 2 30 m in, Fenton pH , pH = 6, Fenton Fen ton 75% II, 20 mm ol/L 05~ 25 mmol/L, FeNTA Fenton II X703 A 2006) Decolorization of dye orange II solu tion by m odified F en ton reaction Zhang D ao in ZhangHu i Zen Zhwi u L i Chuang ( Departm ent ofEnvironm ental Science and Engineering, Wuhan University, Wuhan 430079) Abs tract Decolorization of orange IIw as carried out inw ater using hydrogen peroxide and solu le Fe( III) chelates of n itrilotriacetic acid. The optmi al operating cond itions of decolorization efficiency w ere determ ined y orthogonal expermi ents as follow ing: [ H O ] = 20 mmol/L, [ FeNTA ] = 2. 5 mmol/L, and pH = 3. Furthermore 2 2 the effects of reaction tmi e, pH, hydrogen peroxide dosage and FeNTA concentration on decolorization efficacy w ere investigated. It show ed that the decolorization reactionw as nearly completedw ith in 30 m inutes. O ver 80% decolorization efficiency w as ach ieved in the w ider range of pH when modified Fenton reagent w as employed. Comparedw ith classical Fenton reagent, the decolorization efficiency increased y a out 75% at circumneutral pH of 6. The increase of hydrogen peroxide dosage would increase the decolorization efficacy, ut the effect of hydrogen peroxide ecam e insignificant w hen the concentratio