Analysis of Nonlinear Dynamics for Abrupt Change of Interphase Structure in Liquid-Liquid Mass Transfer英文文献资料.docVIP

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Analysis of Nonlinear Dynamics for Abrupt Change of Interphase Structure in Liquid-Liquid Mass Transfer英文文献资料.doc

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Analysis of Nonlinear Dynamics for Abrupt Change of Interphase Structure in Liquid-Liquid Mass Transfer英文文献资料

HindawiPublishingCorporation MathematicalProblemsinEngineering Volume2009,ArticleID823452,13pages doi:10.1155/2009/823452 ResearchArticle AnalysisofNonlinearDynamicsfor AbruptChangeofInterphase Structurein Liquid-Liquid MassTransfer DongXiangZhang, MinSun, andJingLi 1 2 2 1SchoolofChemicalEngineering andtheEnvironment, BeijingInstituteofTechnology, Beijing100081,China 2CollegeofAppliedScience,BeijingUniversity ofTechnology,Beijing100124,China Correspondence shouldbeaddressedtoJingLi,leejing@ Received22December 2008;Revised30April2009;Accepted 4May2009 Recommended byElbertE.NeherMacau Asaliquid-liquid systemisfarfromequilibrium state,thephasethickness isvariable whenmass transfer process with chemical reaction occurs in interphase zone, and a dispersible transitional layer called the interphase dispersed zone IDZ is formed. The IZD model composed of thermodynamically instable O/W or W/O microemulsion has reasonably explained enormous experimental phenomena innonlinear masstransfer.Toforecastthepossible parameter rangesof IDZprocess andabrupt change ofliquid-liquid masstransfer rate,thedynamic characteristics of a molecular di?usion model are considered in this paper. We applied the bifurcation theory of planar dynamical system, Laplace transform, and maple software to investigate the model, and obtaindi?erentphaseportraitsofthesystemindi?erentregions.Theresultsobtainedwillplayan important directiveroleinthestudyofIDZmodel. Copyright q2009DongXiang Zhangetal. This is an open access article distributed under the Creative Commons Attribution License, which permits unrestricted use, distribution, and reproduction inanymedium,providedtheoriginalworkisproperlycited. 1.Introduction Liquid-liquidmasstransferandreactionmasstransferprocessesarewidelyusedinmany industries such as nuclear energy, hydrometallurgy, pharmaceutical, and chemical. In researchonproductionprocesscontrolandtechniques,wefoundthatinterphaseprocesses are mai