Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films英文文献资料.docVIP

Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films英文文献资料.doc

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Anion Effect of Zinc Source on Chemically Deposited ZnS(O,OH) Films英文文献资料

HindawiPublishingCorporation AdvancesinMaterialsScienceandEngineering Volume2009,ArticleID372708,5pages doi:10.1155/2009/372708 ResearchArticle AnionEffectofZincSourceonChemicallyDeposited ZnS(O,OH)Films K.Ernits,K.Muska,M.Danilson,J.Raudoja,T.Varema,O.Volobujeva,andM.Altosaar DepartmentofMaterialScience,TallinnUniversityofTechnology,Ehitajatetee5,Tallinn19086,Estonia CorrespondenceshouldbeaddressedtoK.Ernits,whiisu@ Received19August2009;Accepted2December2009 RecommendedbyStevenSuib Thestudyontheanione?ectofdi?erentZnsources—Zn(CH3COO)2,ZnCl2,ZnI2,Zn(NO3)2 andZnSO4—onthechemical depositionofZnS(O,OH)?lmsrevealedthatthegrowthrateandcompositionoftheZnS(O,OH)layerdependontheinstability constant(pK)valueofthecorrespondingZn-complexZn(L)ninthechemicalbathsolution.IntheregionofpKZn(NH3)2+pKZn(L)n theZnS(O,OH)?lm’sgrowthrateandZnSconcentrationin?lmsincreasedwiththeincreasingpKvalueoftheusedZnsalt complexuptothepKvalueoftheZn[NH3]2+complexanddecreasedintheregionwherepKZn(NH3)2+ pKZn(L)n.Thebandgap values(around3.6eVinmostcases)ofdepositedZnS(O,OH)?lmsdidnotdependontheZnprecursor’sinstabilityconstant, theZnS(O,OH)?lmfromzincnitratecontainingbathhashigherbandgapenergy(Eg =3.8eV).Themaximume?ciencyof CISSeandCZTSSemonograinlayersolarcellswasgainedwithZnS(O,OH)bu?erlayerdepositedfromCBDsolutioncontaining Zn(CH3COO)2 asZnsource,whichprovidedthehighestgrowthrateandZnSconcentrationintheZnS(O,OH)?lmonglass substrates. Copyright?2009K.Ernitsetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense,which permitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. 1.Introduction solutiononthin?lmparameterswasstudied[5–7].Eshuis et al. [5] pointed out that the chemical nature of used anions controls the growth rate, and morphology of ZnS particles.SeveralauthorshavestudiedCdS?lmsdeposited fromdi?erentcadmiumsaltsinammoniasolutions[8–10] and ZnO deposition from di?erent zinc sources [11] as well.

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