Application of H-Point Standard Addition Method and Multivariate Calibration Methods to the Simultaneous Kinetic-Potentiometric Determination of Cerium(IV) and Dichoromate英文文献资料.docVIP

American Journal of Analytical Chemistry, 2010, 2, 73-82 doi:10.4236/ajac.2010.12010 Published Online August 2010 (http://www.SciRP.org/journal/ajac) Application of H-Point Standard Addition Method and Multivariate Calibration Methods to the Simultaneous Kinetic-Potentiometric Determination of Cerium(IV) and Dichoromate Mohammad Ali Karimi *, Mohammad Hossein Mashhadizadeh , 1,2 3 4 2 Mohammad Mazloum-Ardakani Department of Chemistry Nanoscience and Nanotechnology Research Laboratory (NNRL), Faculty of Sciences, Payame Noor University (PNU), Sirjan, Iran , Fatemeh Rahavian 1 2 Department of Chemistry, Faculty of Sciences, Payame Noor University (PNU), Ardakan, Iran Department of Chemistry, Tarbiat Moallem University of Tehran, Tehran, Iran Department of Chemistry, Faculty of Sciences, Yazd University, Yazd, Iran E-mail: ma_karimi43@ m_karimi@pnu.ac.ir 3 4 Received June 27, 2010; revised July 20, 2010; accepted July 26, 2010 Abstract A kinetic-potentiometric method for simultaneous determination of Cerium(IV) and dichoromate (Cr2O7 ) 2- by H-point standard addition method (HPSAM), partial least squares (PLS) and principal component regres- sion (PCR) using fluoride ion-selective electrode (FISE) is described. In this work, the difference between 4+ 2- the rate of the oxidation reaction of Fe(II) to Fe(III) in the presence of Ce and Cr2O7 is based of the method. The rate of consume fluoride ion for making complex is detected with a FISE. The results show that 4+ 2- simultaneous determination of Ce and Cr2O7 can be done in their concentration ranges of 1.0-30.0 and 0.1-20.0 μg/mL, respectively. The total relative standard error for applying the PLS and PCR methods on 8 synthetic samples was 2.97 and 3.19, respect