Binuclear Cu(II) and Co(II) Complexes of Tridentate Heterocyclic Shiff Base Derived from Salicylaldehyde with 4-Aminoantipyrine英文文献资料.docVIP

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Binuclear Cu(II) and Co(II) Complexes of Tridentate Heterocyclic Shiff Base Derived from Salicylaldehyde with 4-Aminoantipyrine英文文献资料.doc

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Binuclear Cu(II) and Co(II) Complexes of Tridentate Heterocyclic Shiff Base Derived from Salicylaldehyde with 4-Aminoantipyrine英文文献资料

HindawiPublishingCorporation BioinorganicChemistryandApplications Volume2012,ArticleID601879,6pages doi:10.1155/2012/601879 ResearchArticle BinuclearCu(II)andCo(II)ComplexesofTridentateHeterocyclic ShiffBaseDerivedfromSalicylaldehydewith4-Aminoantipyrine OmarHamadShihabAl-Obaidi ChemistryDepartment,CollegeofEducationforWomen,Al-AnbarUniversity,Ramadi,Iraq CorrespondenceshouldbeaddressedtoOmarHamadShihabAl-Obaidi,dromaralobaidi@ Received24September2011;Revised26December2011;Accepted28December2011 AcademicEditor:NickKatsaros Copyright?2012OmarHamadShihabAl-Obaidi. This is an open access article distributed under the Creative Commons AttributionLicense,whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkis properlycited. NewbinuclearCo(II)andCo(II)complexesofONOtridentateheterocyclicSchi?basederivedfrom4-aminoantipyrinewith salicylaldehydehavebeensynthesizedandcharacterizedonthebasesofelementalanalysis,UV-Vis.,FT-IR,andalsobyaidof molarconductivity measurements,magnetic measurements, andmeltingpoints.Ithasbeen foundthattheSchi? baseswith Cu(II)orCo(II)ionformingbinuclearcomplexeson(1:1)“metal:ligand”stoichiometry.Themolarconductancemeasurements ofthecomplexesinDMSOcorrespondtobenonelectrolyticnatureforallpreparedcomplexes.Distortedoctahedralenvironment issuggestedformetalcomplexes.Atheoreticaltreatmentoftheformationofcomplexesinthegasphasewasstudied,andthis wasdonebyusingtheHyperChem-6programforthemolecularmechanicsandsemi-empiricalcalculations.Thefreeligandand itscomplexeshavebeentestedfortheirantibacterialactivitiesagainsttwotypes ofhumanpathogenicbacteria:the?rsttype (Staphylococcusaureus)isGrampositiveandthesecondtype (Escherichiacoli)isGramnegative(byusingagarwelldi?usion method).Finally,itwasfoundthatcompoundsshowdi?erentactivityofinhibitionongrowthofthebacteria. 1.Introduction 2.Experimental 2.1.PhysicalMeasurements. AFisher-100 infrared spectro- photometer was used to record the IR spectra as KBr and CsI