Biosorption of Lanthanides from Aqueous Solutions Using Pretreated Buccinum tenuissimum Shell Biomass英文文献资料.docVIP
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Biosorption of Lanthanides from Aqueous Solutions Using Pretreated Buccinum tenuissimum Shell Biomass英文文献资料
HindawiPublishingCorporation
BioinorganicChemistryandApplications
Volume2010,ArticleID804854,10pages
doi:10.1155/2010/804854
ResearchArticle
BiosorptionofLanthanidesfromAqueousSolutionsUsing
PretreatedBuccinumtenuissimumShellBiomass
YusukeKoto, NaokiKano, YudanWang, NobuoSakamoto, andHiroshiImaizumi
1 2 1 1 2
1
2
GraduateSchoolofScienceandTechnology,NiigataUniversity,Ikarashi2-nocho8050,Nishi-Ku,Niigata950-2181,Japan
FacultyofEngineering,NiigataUniversity,Ikarashi2-nocho8050,Nishi-Ku,Niigata950-2181,Japan
CorrespondenceshouldbeaddressedtoNaokiKano,kano@eng.niigata-u.ac.jp
Received14June2010;Accepted14September2010
AcademicEditor:LorenzoPellerito
Copyright?2010YusukeKotoetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense,
whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited.
Biosorption experiment from aqueous solutions containing known amount of rare earth elements (REEs) using pre-treated
Buccinum tenuissimum shell was explored to evaluate the e?ciency of shell biomass as sorbent for REEs. In this work, four
kindsofsievedshellsamples:(a)“Groundoriginalsample”,(b)“Heat-treatment(480 C,6hours)sample”,(c)“Heat-treatment
?
(950
?
?
C,6hours)sample”and(d)“Heat-treatment(950 C,6hours)andwateraddedsample”wereused.Furthermore,tocon?rm
thecharacteristicsoftheshellbiomass,thecrystalstructure,thesurfacemorphology,andthespeci?csurfaceareaoftheseshell
samplesweredetermined.Consequently,thefollowingmattershavebeenmainlyclari?ed.(1)Thecrystalstructureoftheshell
biomasswastransformedfromaragonite(CaCO3)intocalcite(CaCO3)phasebyheat-treatment(480
transformedintocalciumoxide(CaO)byheat-treatment(950 C,6hours),andcalciumhydroxide(Ca(OH)2)byheat-treatment
C,6hours)andaddingwater.(2)Theshellbiomassshowedexcellentsorptioncapacityforlanthanides.(3)Adsorption
isothermsusingtheshellbiomasscanbedescribedbyLangmuirandFreundlichisoth
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