Degrading Endocrine Disrupting Chemicals from Wastewater by Photocatalysis A Review 外文参考文献.docVIP

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Degrading Endocrine Disrupting Chemicals from Wastewater by Photocatalysis A Review 外文参考文献.doc

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Degrading Endocrine Disrupting Chemicals from Wastewater by Photocatalysis A Review 外文参考文献

HindawiPublishingCorporation InternationalJournalofPhotoenergy Volume2012,ArticleID185159,23pages doi:10.1155/2012/185159 ReviewArticle DegradingEndocrineDisruptingChemicalsfromWastewaterby TiO2Photocatalysis:AReview Jin-ChungSin,Sze-MunLam,AbdulRahmanMohamed,andKeat-TeongLee SchoolofChemicalEngineering,UniversitiSainsMalaysia,EngineeringCampus,14300NibongTebal,Malaysia CorrespondenceshouldbeaddressedtoAbdulRahmanMohamed,chrahman@eng.usm.my Received13June2011;Revised3August2011;Accepted4August2011 AcademicEditor:JiaguoYu Copyright?2012Jin-ChungSinetal.ThisisanopenaccessarticledistributedundertheCreativeCommonsAttributionLicense, whichpermitsunrestricteduse,distribution,andreproductioninanymedium,providedtheoriginalworkisproperlycited. Widespreadconcernscontinuetoberaisedabouttheimpactsofexposuretochemicalcompoundswithendocrinedisrupting activities.Todate,thepercolationofendocrinedisruptingchemical(EDC)e?uentintotheaquaticsystemremainsanintricate challengeabroadthenations.Withtheinnovationofadvancedoxidationprocesses(AOPs),therehasbeenaconsistentgrowing interestinthisresearch?eld.Hence,theaimofthispaperistofocusonesuchmethodwithintheAOPs,namely,heterogeneous photocatalysis and how it is used on the abatement of EDCs, phthalates, bisphenol A and chlorophenols in particular, using TiO2-basedcatalysts.Degradationmechanisms,pathways,andintermediateproductsofvariousEDCsforTiO2 photocatalysis aredescribedindetail.Thee?ectofkeyoperationalparametersonTiO2 photocatalyticdegradationofvariousEDCsisthen speci?callycovered.Finally,thefutureprospectstogetherwiththechallengesfortheTiO2photocatalysisonEDCsdegradationare summarizedanddiscussed. 1.Introduction functionviamodesofactionsuchasmimickingendogenous hormones, antagoniting of hormone receptors, disrupting hormone secretion or metabolism, or disrupting natural hormoneproductionpathways[9,10].Endocrinedisruptors are also hypothesized to play a role in the pathogenesis of various disorders including male and femal