活性炭负载钛酸四丁酯催化合成二甘醇二苯甲酸酯.pdfVIP

学兔兔 化 工 进 展 2014年第33卷第5期 CHEMICAL INDUSTRYAND ENGINEERING PRCIGRESS ·1201· 活性炭负载钛酸四丁酯催化合成二甘醇二苯甲酸酯 陈慕华，陈燕青，陈思，朱新宝 (南京林业大学化工学院，江苏南京210037) 摘要：以活性炭负载钛酸四丁酯[Ti(0Bu)4／Ac]为催化剂，用于催化合成二甘醇二苯甲酸酯(DEDB)。通过实验 确定了合成DEDB的适宜工艺条件：n(BA)：n(DEG)=2：1、催化剂用量为1．25％，带水剂用量为20．0％，反应 温度为200~C，反应时间为7h，该反应条件下酯化率可达98．1％。催化重复使用实验表明该催化剂具有良好的稳 定性。同时建立了该酯化合成的表观动力学模型，得到反应速率方程为：rA：6．28×109exp- cA 。 』【』 关键词：钛酸四丁酯；固载催化剂；活性炭；二甘醇二苯甲酸酯 中图分类号：TQ 225．24 文献标志码：A 文章编号：1000—6613(2014)05—1201—05 DOI：l0．3969~．issn．1000—6613．2014．05．020 Synthesis of diethylene glycol dibenzoate catalyzed by Ti(OBu)4／AC CHENMuhua，CHENYanqing，CHENSi，ZHUXinbao (School ofChemical Engineering，Nanjing Forestry University，Nanjing 210037，Jiangsu，China) Abstract：Diethylene glycol dibenzoate was synthesized by the reaction of benzoic acid(BA)with diethylene glycol(DEG)using Ti(OBu)4／AC as catalyst．The optimal reaction condition was found as： the molar ratio of benzoic acid to diethylene glycol was 2：1，the mass ratio of catalyst to benzoic acid was 1．25％，the mass ratio ofbutyl ether to benzoic acid was 20％，reaction temperature was 200~C， and reaction time was 7h．The optimal esterification rate was up to 98．1％．After three times ofrepeated use，the esterification yield still maintained above 97％．The apparent kinetics model of esterification was established，and the equation of reaction rate was： ：6．28×1 09exp一 CB． 』 Key words：tetrabutyl titanate；supported catalyst；