SO4 2-／ZrO2／凹土纳米固体酸催化剂的制备及其催化合成乙酸正丁酯.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第4期 PETR0CHEMICAL TECHN0L0GY ·365· so 一／ZrO2／凹土纳米固体酸催化剂的制备及其 催化合成乙酸正丁酯 蒋金龙，钱运华，固 旭 (淮阴工学院 生命科学与化学工程学院 江苏省凹土资源利用重点实验室，江苏 淮安 223003) 摘要]以凹凸棒石黏土(简称凹土)为载体，采用沉淀法制备了sol一／ZrO2／凹土纳米固体酸催化剂；采用XRD，EDX，TEM等方 法对催化剂进行了表征；考察了载体、催化剂制备条件对催化剂催化乙酸与正丁醇进行酯化反应合成乙酸正丁酯的影响。实验结 果表明，pq土晶体纤维表面高度分散的ZrO 纳米粒子与凹土的协同作用使sot一／ZrO ／凹土纳米固体酸催化剂具有很好的活性。 在nl(ZrO2)：m(凹土)：1：2、煅烧温度500℃、煅烧时间3 h的条件下制备的sol／ZrO2／凹土纳米固体酸催化剂的活性最高； 在乙酸0．50 tool、正丁醇0．55 tool、催化剂0．6 g、反应温度120℃和时间90 rain的条件下，酯化率町达90．34％；该催化剂具有较 好的稳定性，重复使用4次其催化活性摹本保持稳定。 [关键词]凹凸棒石黏土；固体酸催化剂；乙酸；正丁醇；乙酸正丁酯 [文章编号]1000—8144(2011)04—0365—04 [中图分类号：TQ 255．24 [文献标识码]A Preparation of Nano Solid Acid Catalyst sol一／ZrO2／Palygorskite and Its Application to Synthesis of Butyl—Acetate Jiang Jinlong，Qian Yunhua，Gu Xu (Faculty of Life ScienceChemical Engineering，Huaiyin Institute of Technology，Key Laboratory for Palygorskite Science and Applied Technology of Jiangsu Province，Huaian Jiangsu 223003，China) [Abstract] Nano solid acid catalyst so24一／ZrO2／palygorskite was prepared by a precipitation method with palygorskite as the support．The catalyst was characterized by means of XRD，EDX and TEM ， and used in synthesis of butyl acetate from acetic acid and n—butano1．The effects of the support and the preparation conditions on the synthesis were investigated．The results showed that the prepared catalyst exhibited high catalytic activity in the synthesis because of the synergistic effect between the highly surface—dispersed ZrO2 nanoparticles and the palygo