V（Ⅲ）-V（Ⅳ）电解液的化学合成及性能.pdfVIP

学兔兔 化 工 进 展 ‘1330‘ CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2012年第3 1卷第6期 V(III)．v(1V)电解液的化学合成及性能 陈孝娥，崔旭梅，王 军 (攀枝花学院钒钛材料省级工程技术中心，四川 攀枝花 617000) 摘 要：钒电池是一种高效储能装置，钒电池电解液直接影响电池性能。本文以V2O3、V2O5和H2s04为原料， 化学合成了用于钒电池的v(III)．V(IV)电解液，研究了无水乙醇与焦磷酸钠作为添加剂对电解液稳定性和电化学 活性的影响。实验结果表明，当V203／V205质量比为7．2：1时，可以得到V(III)~(N)g子浓度比为1．0的电解 液；添加剂的加入能提高电解液的稳定性和电化学反应活性。 关键词：钒电池；电解液；添加剂；稳定性 中图分类号：O 614．51 1 文献标志码：A 文章编号：1000—6613(2012)06—1330—03 Study on the chemical synthesis and the performance of V(III)一v(Ig) electrolyte CHENXiao e，CUIXumei，WANGJun (Engineering Technology Research Center ofVanadium—Titanium Materials of Sichuan Province， Panzhihua University，Panzhihua 617000，Sichuan，China) Abstract：Vanadium redox flow battery is a highly efficient storage energy installs．The electrolyte influence the battery capacity directly．V(III)-v(iv)electrolyte of vanadium redox flow battery was prepared by chemical method with V2O3，V205 and H2SO4 in this paper．The impacts of the additives of alcohol and sodium pyrophosphate on the stability and the electrochemical activity of electrolyte were investigated．The experimental results showed that the electrolyte with v(III)／v(1V)concentration ratio of 1．0 was acquired with the V203／V205 mass ratio of 7．2：1．And the stability and the electrochemical activity ofthe electrolyte were improved by adding the additives． Key words：vanadium redox flow battery；electrolyte；additive；stability 近年来，世界能源的紧缺及环境污染的不断加 山梨醇的加入不仅能改善v(v)的溶解性，还能提高