LK-C2萃取分离废线路板酸浸液中的铁和镍.pdfVIP

学兔兔 化 工 进 展 2009年第28卷第4期 CHEMICAL INDUSTRY AND ENGINEERING PR0GRESS ·703· LK．C2萃取分离废线路板酸浸液中的铁和镍 张小娟1，李鑫钢 ，一，曹宏斌 ( 天津大学化工学院，天津 300072； 天津大学精馏技术国家工程研究中心，天津 300072； 中国科学院过程 工程研究所绿色过程工程院重点实验室，北京 100090) 摘 要：针对废线路板酸浸液的硝酸介质体系，探讨了用LK—C2分离铁 (III)和镍的萃取及反萃条件。pH值为 3．00和 10．00时分步采用20％LK—C2一煤油二级逆流萃取铁 (III)和镍，萃取率分别为96．14％和99．35％。分别采 用2．00mol／LHC1二级逆流反萃回收铁和3．00mol／LH2S04三级逆流反萃回收镍，反萃率分别为99．18％和98．32％。 关键词：LK—C2；萃取；铁；镍 中图分类号：TF 804．2；X 705；X 76 文献标识码：A 文章编号：1000—6613(2009)04—0703—05 Separation of Fe and Ni by solvent extraction with LK-C2 from nitric acid leaching solution of wasted printed circuit boards ZHANGXiaojuan ，LIXingang ，CAO Hongbin ( School of Chemical Engineering and Technology，Tianjin University，Tianjin 300072，China； National Engineering Research Center ofDistillation Technology，Tianjin University，Tianjin 300072，China； Key Laboratory of Green Process and Engineering，Institute of Process Engineering，Chinese Academy of Sciences，Beijing 100090，China) Abstract：LK．C2 was used to separate Fe and Ni from me nitric acid leaching solution of wasted printed circuit boards．Fe and Ni were extracted by using 2O％ LK—C2 in kerosene countercurrently at two stages at DH=3．O0 and 10．00，and the extraction rates were 96．14％and 99．35％，respectively．Fe was stripped by 2。OOmol／L HC1 countercurrently at two stages and the stripping rate was 99．1 8％．Ni was stripped by 3．00mol／L H2SO4 countercurrently at three stages and the stripping rate was 98．32％． Key words：LK—C2；solvent ex仃action：iron；nickel 随着电子设备更新换代速度的加快，电子废弃物