Rauniticine-allo-Oxindole B and Rauniticinic-allo Acid B, New Heteroyohimbine-Type Oxindole Alkaloids from the Stems of Malaysian Uncaria longiflora var. pteropoda 英文参考文献.docVIP

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Rauniticine-allo-Oxindole B and Rauniticinic-allo Acid B, New Heteroyohimbine-Type Oxindole Alkaloids from the Stems of Malaysian Uncaria longiflora var. pteropoda 英文参考文献.doc

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Rauniticine-allo-Oxindole B and Rauniticinic-allo Acid B, New Heteroyohimbine-Type Oxindole Alkaloids from the Stems of Malaysian Uncaria longiflora var. pteropoda 英文参考文献

Molecules 2011, 16, 6541-6548; doi:10.3390/moleculeOPEN ACCESS molecules ISSN 1420-3049 /journal/molecules Article Rauniticine-allo-Oxindole B and Rauniticinic-allo Acid B, New Heteroyohimbine-Type Oxindole Alkaloids from the Stems of Malaysian Uncaria longiflora var. pteropoda Fatimah Salim 1, Nor Hadiani Ismail 1, Khalijah Awang 2 and Rohaya Ahmad 1,* 1 Faculty of Applied Sciences, Universiti Teknologi MARA, 40450 Shah Alam, Selangor, Malaysia; E-Mails: fatimahsalim10@ (F.S.); norhadiani@.my (N.H.I.) 2 Department of Chemistry, Universiti Malaya, Kuala Lumpur 50603, Malaysia; E-Mail: khalijah@.my (K.A.) * Author to whom correspondence should be addressed; E-Mail: rohayaahmad@.my; Tel.: +603 Fax: +603 Received: 20 June 2011; in revised form: 15 July 2011 / Accepted: 20 July 2011 / Published: 4 August 2011 Abstract: Two new heteroyohimbine-type oxindole alkaloids, rauniticine-allo-oxindole B and rauniticinic-allo acid B, have been successfully isolated from the stems extract of Malaysian Uncaria longiflora var. pteropoda. The structures of the two new alkaloids were determined by spectroscopic analysis. Keywords: Uncaria longiflora; rubiaceae; oxindole alkaloids; heteroyohimbine; rauniticine-allo-oxindole B; rauniticinic-allo acid B 1. Introduction Uncaria (family Rubiaceae) is a genus of woody climber plants comprising 34 species. The plants of the genus are mainly distributed in tropical regions, including Southeast Asia, Africa and Southeast America. Of these, about 10 species of Uncaria are found in Malaysia and Uncaria longiflora var. pteropoda is one of the representatives [1,2]. Traditionally, the leaves of Uncaria longiflora var. pteropoda are rubbed on the body to relieve pain from rheumatism, while its juice is used for thrush and mixed with iron-rust for framboesia [1]. Early chemical investigations on this plant have led to the isolation of two heteroyohimbi