聚苯乙烯磺酸钠复合物的湿敏特性.pdfVIP

第24卷 第4期 传 感 技 术 学 报 Vo1．24 No．4 2011年 4月 CHINESE JOURNALOF SENSORSAND ACTUATORS Apr．2011 Humidity SensitivePropertiesofa CompositeofSodium Poly(Styrene-Alt-MaleicAnhydride)andPolystyrenesulfonate L／URuowang，LIYang ，rANGMujie 12．MZhO~EiaKngeyULnabvioerrastityo三ryH，oafngzhcⅡouu，3010zles0cEM2n7z0gr，CniSheyennirtahniges,iWsaenndzhFouunUcntiovineraslitizya,tWionenD，，zheopu．ar3tm25e0n2t7o一,fCPhonilyame；rSciem：enⅡdEn—gni一eer一nig．]1／ Abstract：Resistive—typehumiditysensorsbasedonacompositeofsodium poly(styrene—ah—maleicanhydride) (NaSMA)andsodiump0lystyrenesulf0nate(NaPSS)werefabricatedbydipcoatingtheaqueoussolutionoftheeom． positeontointerdigitatedgoldelectrodes．TheeffectoftheconcentrationofbothNaSMA andNaPSSonthehumidity sensingpropertiesofthecompositesensorshasbeeninvestigatedoverawiderangeofrelativehumidity(RH)(33％ RH～97％ RH)．ItwasfoundthattheintroductionofNaPSSintothecompositenotonlydecreasedtheimpedance ofthecompositeatlow humiditybutalsoimprovedthesensitivity athighhumidity．Underoptimalconditions，the compositesensorexhibitedimpedancechangefrom 4．2x10 n to1．8x10 Q whenhumidityincreasedrfom 33％ RH ～97％ RH ，showinghigh sensitivity．Moreover，goodsensinglinearityonasemi—logarithmicscaleandrelatively smallhysteresiswereobserved．Thecompositehumiditysensorshowedbettersensingpropertiesthan thatbasedon NaSMA orNaPSSalone．Inaddition，itwasfound thatapplyingaprotectivelayerofsilicone—acrylicresin onthe compositesensoritsstabilityunderhumidenvironmentcanbegreatlyimproved． Keywords：humiditysensor；polymercomposite；humiditysensitiveproperties；sodium polystyrenesulfonate；sodium poly(styrene—ah—maleicanhydride) EEACC：7320X；7230L doi：10．3969／j．issn．1004—1699．2011．04．004 苯 乙烯一马来酸酐交替共聚物钠盐 ／聚苯乙烯 磺酸钠复合物 的湿敏特性 刘若望 ，李 扬 ，杨慕杰 ，1．温州大学化学与