Spectroscopic Characteristics of Highly Selective Manganese Catalysis in Acqueous Polyurethane Systems 英文参考文献.docVIP

Sensors 2006, 6, 1708-1720 sensors ISSN 1424-8220 ? 2006 by MDPI /sensors Full Paper Spectroscopic Characteristics of Highly Selective Manganese Catalysis in Acqueous Polyurethane Systems Suzana Cakic 1, Caslav Lacnjevac 2,*, Goran Nikolic 1, Jakov Stamenkovic 1, Milos B. Rajkovic 2, Miladin Gligoric 3 and Miroljub Barac 2 1 Faculty of Technology, 16000 Leskovac, Bul. oslobodenja 124, Serbia; E-mails: suzana_cakic@ (Suzana Cakic), goranchem_yu@ (Goran Nikoli?), jakov.stamenkovic@le.sbb.co.yu (Jakov Stamenkovic) 2 Faculty of Agriculture, 11080 Belgrade-Zemun, St. Nemanjina 6, Serbia; E-mails: ukilaki@eunet.yu (Caslav Lacnjevac), rajmi@agrifaculty.bg.ac.yu (Milos B. Rajkovic), baracm@agrifaculty.bg.ac.yu (Miroljub Barac) 3 Faculty of Technology, 56000 Zvornik, Karakaj bb, Srpska Republic, E-mail: lcaja@agrifaculty.bg.ac.yu (Miladin Gligoric) *Author to whom correspondence should be addressed; E-mail: lcaja@agrifaculty.bg.ac.yu or ukilaki@eunet.yu Received: 25 September 2006 / Accepted: 12 November 2006 / Published: 20 November 2006 Abstract: The latest investigations on producing more efficient catalytic aqueous polyurethane systems are in the domain of metal complexes with mixed ligands. In our previous research works, the high selectivity for the isocyanate-hydroxyl reaction in aqueous polyurethane systems has been shown by the manganese(III) mixed-ligand complexes. The two new complexes have been prepared with two acetylacetonate (acac) ligands and one maleate ligand and its hydroxylamine derivative of the general formula [Mn(C5H7O2)2L]. Their structures have been established by using the fundamental analyses, the FTIR and UV/VIS spectroscopic methods, as well as the magnetic measurements. In order to explain the different selectivity of the manganese(III) mixed-ligand complexes, the UV and ESR spectroscopy have been employed to determine the kinetics of the complexes’ decompo