离子液体在可逆加成-断裂链转移聚合中的应用.pdfVIP

• 47 • 离子液体在可逆加成-断裂链转移聚合中的应用/赵 欣等 离子液体在可逆加成·断裂链转移聚合中的应用 赵欣，吴琦，魏坷瑶，段然，孙跃文，李海英，雷良才 (辽宁石油化工大学化学化工与环境学部，抚顺 113001) 摘要 离子液体具有优良的物理化学性能，受到研究者的广泛关注。近年来，有关离子液体在可逆加成断裂 链转移(RAFT)聚合反应中的应用有大量的研究报道。作为溶剂，离子液体能溶解一些较难溶解的聚合物，如纤维 索和壳聚糖等，可以为聚合反应提供较好的反应环境;作为单休，通过 RAFT 聚合可制备出聚合离子液体均聚物或 带有聚合离子液体链段的嵌段聚合物，可以应用于燃料电池电解质膜、太阳能电池、催化、分离及吸m剂等领域;离子 液体还可以作为表面活性剂，应用于 RAFT 的乳液聚合或细乳液聚合，有效地稳定和控制聚合物颗粒大小。从溶 剂、单体和表面活性剂方面出发，简单总结了离子液体在 RAFT 聚合反应中的应用。 关键词 可逆加成断裂链转移聚合离子液体溶剂单体表面活性剂 中图分类号:TQ317.9 文献标识码:A 四)1: 10. 11896/j. iss几 1005-023X. 2015.023.009 Application of Ionic Liquid in the Reversible Addition-Fragmentation Chain Transfer Polymerization ZHAO Xin , WU Qi , WEI Keyao , DUAN Ran , SUN Yuewen , LI Haiying , LEI Liangcai (College of Chemistry ,Chemical Engineering and Environmental Engineering , Liaoning Shihua University , Fushun 113001) Abstract Ionic liquid has unique physical and chemical properties , which have been widely concerned by re- searchers. In recent years , the application of ionic liquids in the reversible addition fragmentation chain transfer (RAFT) polymerization has a large number of studies. Ionic liquids can be as solvent , not only can dissolve some dif ficu\t dissolved polymer. such as cellulose , chitosan and so on , but also provide better reaction condition for polymeri zation reactio n. As monomer , it can synthesize homopolymer and io口ic liquid chains of the block copolymer , which is widely applied in the areas of fuel cell e1ectrolyte film , solar cell , catalysis , separation and adsorption agents. lt used as surfactant in RAFT emulsion polymerization or miniemulsion polyme