ZrB2-SiC复相陶瓷的制备及其耐热冲击性能的研究.pdfVIP

维普资讯 学兔兔 第26卷第4期 粉末冶金技术 Vo1．26，NO．4 2008年8月 Powder Metallurgy Technology Aug．2008 ZrB2一SiC复相陶瓷的制备及其耐热冲击性能的研究 毛小东 白 玲 沈卫平一 燕青芝 葛昌纯 (北京科技大学特种陶瓷与粉末冶金研究室，北京 100083) 摘 要： 以Zr—B203一Mg为反应体系，利用自蔓延高温合成法(SHS)制备 ZrB2粉体。分别在反应前和反 应后掺人(体积分数)20％SiC，利用放电等离子烧结技术(SPS)制备ZrB2一SiC超高温陶瓷。采用SEM观察 显微组织，利用阿基米德法测定密度，用氧炔焰进行热冲击试验。结果表明：与在自蔓延生成 ZrB2后再掺人 SiC的粉体相比，在自蔓延体系中直接掺人SiC粉体能够改善SiC的烧结活性及分散均匀程度，从而使相同烧 结工艺下制备的ZrB2一SiC复相陶瓷具有较高的致密度和更好的抗热冲击性能。 关键词：超高温陶瓷；ZrB2一SiC；自蔓延合成；放电等离子烧结；热冲击性能 Preparation of ZrB2——SiC ceramic composites and testing of its resistance to thermal shock Mao Xiaodong，Bai Ling，Shen Weiping，Yah Qingzhi，Ge Changchun (Laboratory of Special Ceramics and Powder Metallurgy，University of Science and Technology Beijing，Beijing 100083，China) Abstract：ZrB2 and SiC composite powder(80vo1．％Zrt?~+20vo1．％sic)was prepared by self—propagation high— temperature synthesis(SHS)using raw materials of Zr—B203一Mg。with SiC as pre-mixed inert diluents，which Was then sintered at the temperature of 1700℃ by the methods of spark plasma sintering (SPS)．The microstructure of samples was observed by SEM．density measured based on Archimedes method and thermal shock resistance tested by oxyacetylene heating．z powder Was synthesized by SHS from Zr—B203 一Mg and then it Was mixed mechanically with SiC．The mechanically mixed powder was sintered under the sam