纳米晶W-10Cu粉末及其烧结行为.pdfVIP

学兔兔 第15卷第4期 粉末冶金材料科学与工程 2010年8月 、，0l_l5 No．4 Materials Science and Engineering of Powder Metallurgy Aug．2010 喷雾干燥一氢还原制备超细／纳米晶W-IOCu粉末 及其烧结行为 朱 松，范景莲，刘 涛，田家敏 (中南大学 粉末冶金国家重点实验室，长沙，410083) 摘 要：采用喷雾干燥一氢还原法制备超细／纳米晶W-10Cu(质量分数，％)复合粉末，并经过压制和烧结制备W-Cu 复合材料，系统研究烧结温度和保温时间对该材料性能和组织的影响，以及在1 100～1 300℃温度范围内的烧结 激活能。结果表明，W-lOCu还原粉末晶粒度仅为30～60 nin；在1 200℃烧结时开始发生明显的致密化行为；随 烧结温度升高相对密度增大，当烧结温度升高到1 300℃时W-IOCu复合材料的相对密度为90％，但当温度达到 1 460℃时有所降低。1 420℃保温90 min时材料相对密度高达99．1％，且此时晶粒度仅为1．8儿m。W晶粒尺寸 为30～60 nlTl的W-lOCu复合粉末在1 100～1 300℃烧结的平均激活能为129．14 kJ／mol。烧结温度为1 420℃时 W-10Cu的电导率随保温时间延长先增大后减小，保温90 min时最大达到19 MS／m，超过国标有关规定。 关键词：W-10Cu复合粉末；超细／纳米晶；烧结致密化；激活能；晶粒长大 中图分类号：TG149．4 ll 文献标识码：A 文章编号：1673—0224(2010)4—373—05 Preparation and sintering behavior of uItra|『ine／nan0crystaUine W-IOCu composite powders ZHU Song，FAN Jing-lian，LIU Tao，TIAN Jia—min (State Key Laboratory ofPowder Metallurgy,Central South University,Changsha 410083，China) Abstract：Ultrafine／Nanocrystalline w一1 OCu(mass fraction，％)composite powders were synthesized by sol—spray drying and subsequent hydrogen reduction process．The W-Cu composite materials were fabricated through pressing and sintering．Effects of Sintering temperature and holding time on material properties and microstructure were systematically studied．The sintering activation energy between 1 100 and 1 300℃ was also explored in the present paper．The results show that the grain size Of W 10Cu powder is only 30-60nm and obvious de