引气剂液膜单分子层及硬化混凝土气孔结构分析.pdfVIP

学兔兔 江苏建筑 2010年第6期(总第 138期) 89 引气剂液膜单分子层及硬化混凝土气孔结构分析 毛良喜，黄志讲，尚燕，丁蓓 (江苏博特新材料有限公司，江苏南京 210008) 『摘 要】 利用膜天平研究了两种引气荆cv9和改性松香R在空气一水界面的液膜单分子层强度，采用光学显微镜测孔 法分析了硬化引气混凝土的气孔结构．并考察了高频振捣对掺 2种引气剂的混凝土气孔结构的影响。结果表明，引气剂在空 气一水界面上的单分子膜强度是影响引气弃】稳泡性能的重要参数之一。掺加稳泡性能优异的高性能引气剂，可以在混凝土中 引入更加细小、稳定、分布合理的气泡，硬化混凝土具有更优化的气孔结构。高频振捣破坏了混凝土中的大直径气泡，合理的 振捣时间优化了混凝土的气孔结构。 『关键词1 单分子膜；引气剂；气孔结构 『中图分类号]TU528．042．4 [文献标识码】A 【文章编号]10O5—627O(2010)O6一o089—04 Anlysis of Monolayer of Air-Entraining Agent and Air Vojd Characteristics of Harden Concrete MAO Liang-xi HUANG Zhi-jiang SHANG Yan DING Bei (Jiangsu Bote New Materials Co．，Ltd，Nanjing Jiangsu 210008 China) Abstract：Monolayer of two kinds of air—entraining agent GYQ and modified rosin R are formed in KSV 2000 Langmuir rain-trough at air-water interface，respectively．The surface pressure of each monolayer is measured using the wilhelmy plate technique． The static surface elasticity of monolayer at air—water interface are dis— cussed by analyzing the 71-一A isotherm．The air void characteristics of hardened concrete are determined by au— tomated linear traverse method with image processing system based on ASTM C 457． It’S found that the per— formance of air bubble stability of air-entraining admixtures iS determined directly by the strength of monolay— er at air—water interface．Comparing with the air void characteristics of hardened concrete produced by air—en— training admixtures，higher strength of GYQ monolayer resulted in the smaller spacing factors and more excel— lent air void characteristics．The bigger air bubbles were broken by the method of high frequency vibration，the air void characteristics of harden concrete were optimized