PLA酸性降解及其机理分析_姜皎洁.pdfVIP

第35卷 第23期 包装工程 2014年12月 PACKAGINGENGINEERING 13 PLA的酸性降解及其机理分析 姜皎洁，刘文涛，唐新颖，任百霞，何素芹，朱诚身 （郑州大学，郑州 450052） 摘要：目的目的研究PLA在酸性条件下降解及其机理。方法方法 通过在酸性水溶液中降解不同时间，得到 一系列不同相对分子质量的PLA，利用黏度法、凝胶色谱以及红外光谱对PLA的降解机理进行研究。 结果结果 PLA的数均分子量随降解时间的增加逐渐减小，失重率和降解率逐渐升高，在降解23d后，产物 的数均分子量从4050降至2490，失重率从9.9%升至75.1%，降解率从98.3%提高至99.0%。降解过程 中，PLA的相对分子质量分布系数基本保持不变，一直维持在1.25左右。结论结论 在降解过程中，酯键的 断裂是PLA初步降解的主要方式，H+浓度的升高有利于催化酯键的断裂，加剧PLA降解。 关键词：PLA；降解；酸性 中图分类号：TB484.6 文献标识码：A 文章编号：1001-3563（2014）23-0013-04 Acid Degradation of PLA and Its Mechanism JIANG Jiao-jie ，LIU Wen-tao ，TANG Xin-ying ，REN Bai-xia ，HE Su-qin ，ZHU Cheng-shen （Zhengzhou University ，Zhengzhou 450052 ，China） ABSTRACT ：Objective To study the acid degradation of PLA and to investigate its mechanism. Methods A series of PLA with different molecular weights were obtained after different degradation time in acidic aqueous solution, followed by viscometric determination, GPC and FTIR to analyze its degradation mechanism. Results The number-average molecular weight of PLA gradually decreased with the increasing degradation time, while the weight-loss rate and degradation rate gradually increased. After 23 d degradation, the number-average molecular weight of PLA diminished from 4050 to 2490, while the weight-loss rate and degradation rate accumulated from 9.9% and 98.3% to 75.1% and 99.0%, respectively. The molecular weight distribution coefficient remained stable at about 1.25 during the degradation. Conclusion The main initial degradation of PLA was the fracture of ester bond, which was accelerated by the concentration enhancement of H+ . As a result, degradation