低温型汽油选择加氢脱双烯脱硫醇催化剂-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第1期 PETROCHEMICAL TECHN0L0GY ·19· 低温型汽油选择加氢脱双烯脱硫醇催化剂 徐国锋，黄星亮，王亭亭 (中国石油大学(JL京)化T学院，北京 102249) [摘要]对以A1，0 为载体的金属氧化物催化剂催化FCC汽油选择性加氢反应进行了研究。考察了单组分、双组分及三组分元 素组合对催化剂选择性加氢脱双烯脱硫醇性能的影响。实验结果表明，双组分催化剂的选择加氢脱双烯脱硫醇的性能明显优 于单组分催化剂；经过适当组合的三组分催化剂的选择加氢脱双烯脱硫醇的性能较好，尤其是TiNiMo／A1 O，催化剂的加氢性 能最好，在高液态空速(9 h。。)下反应100 h，异戊二烯的转化率大于70％，乙醇硫的转化率为100％，总单烯饱和度为0；且该 催化剂还表现出一定的双键异构活性。 [关键词]FCC汽油；选择加氢；氧化铝；乙硫醇；异戊二烯 [文章编号]1000—8144(2013)Ol一0019—05 [中图分类号]TQ 426．83 [文献标志码]A Catalysts of Low Temperature Selective Hydr0genatiOn for Removing Diolefins and Mercaptan in Light Gasoline Xu Guofeng，HuangXingliang，Wang Tingting (College ofChemical Engineering，China Universiy ofPetroleum-Beijing，Beijing 102249，China) l Abstract J Metallic oxide catalysts supported ON A12O3 were prepared and used in the selective hydrogenation of FCC light gasoline．The effects of different element associations on the catalytic performances of the selective hydrogenation catalysts in removing diolefins and mercaptans in the FCC light gasoline were investigated．The results showed that the catalytic perform ances of bi—component catalysts were better than those of mono—component catalysts and the hydrogenation performance of appropriately combined three component catalysts is the best，especially TiNiMo／A1203．Under the conditions of LHSV 9 h～and reaction time 1 00 h，diolefin hydrogenation conversion and mercaptan removal rate can reach more than 70％and 1 00％respectively，the total mono—olefin saturation