分子筛载体对Pt-Sn-Na三组分丙烷脱氢催化剂性能的影响-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 T · 1346· PETROCHEMICAL TECHN0L0GY 2012年第41卷第12期 分子筛载体对Pt—Sn—Na三组分丙烷脱氢 催化剂性能的影响 王秀玲 (中国石化 北京化T研究院，北京 100013) [摘要]采用等体积分步浸渍法，分别以不同 (SiO )：n(A1 O )的ZSM一5和p分子筛以及以一定比例机械混合的ZSM一5和p 分子筛为载体，制备负载型Pt—sn—Na 组分丙烷脱氢催化剂，在固定床微型反应装置上对制备的催化剂进行了丙烷脱氢性能 评价，并采用NH 一TPD方法对催化剂进行了表征。实验结果表明，以 (SiO )： (AI：O )=1o0的ZSM一5分子筛和月(SiO )： n(AI，O )=80的B分子筛进行机械混合得到的混合分子筛为载体，制备的Pt—Sn—Na／ZSM一5一p催化剂的丙烷脱氢性能较好， 在n(H，)：(C H )=1：1、C H 的重时空速2 h～、反应压力0．1 MPa、反应温度600℃的条件下，丙烷转化率约为28．O％，丙 烯选择性大于等于98．6％。 [关键词]ZSM一5分子筛；p分子筛；铂一锡一钠催化剂；丙烯；丙烷脱氢 [文章编号]1000—8144(2012)12—1346—05 [中图分类号]TQ 426．83 [文献标识码]A Effect of Zeolite Support on Catalytic Performance of Pt--Sn--Na Catalyst for Propane DehydrOgenati0n WangXiuling (SINOPEC Beijing Research Institute ofChemical Industry，Beijing 100013，China) [Abstract] Several platinum—tin—sodium catalysts for propane dehydrogenation were prepared on different supports，namely ZSM-5 zeolite，p zeolite and ZSM一5-p with different mass ratio prepared by mechanical mixing，and characterized by means of NH3一TPD．The effects of the zeolite type and n(SiO2)：n(Al203)on the performances of the Pt—Sn—Na catalysts were studied in a fixed bed microreactor．The experimental results showed that the catalyst on the ZSM-5一B support，in which n(SiO2)：n(A12O3)s of ZSM一5 and p were 1 00 and 80 respectively，was excellent in the propane dehydrogenation process．Under the reaction conditions of n(H2)： (C3H8)1：1，C3H8 WHSV 2 h。。