葡萄糖改性聚氨酯微乳液的制备及其膜性能的研究-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2013年第42卷第9期 PETR0CHEMICAL TECHN0L0GY ·979· 葡萄糖改性聚氨酯微乳液的制备 及其膜性能的研究 王 磊 ，赖小娟 ，马少云 (1．陕西科技大学 教育部轻化工助剂化学与技术重点实验室，陕西 西安 710021； 2．延长油田丰源实业总公司 油田化工产品开发中心，陕西 延安 716000) [摘要J以葡萄糖为交联剂对水性聚氨酯进行改性，得到葡萄糖改性聚氨酯微乳液及改性聚氨酯胶膜。利用TEM，FTIR， XRD，TGA等方法研究了葡萄糖改性聚氨酯微乳液的形态，分析了改性聚氨酯胶膜的结构、热稳定性能、耐介质性能及力 学性能。表征结果显示，葡萄糖对水性聚氨酯的改性是通过葡萄糖的羟基与聚氨酯的一NcO基发生反应；随葡萄糖用量的增 加，改性聚氨酯胶膜的热分解温度升高、耐介质性能得到改善、拉伸强度增大、断裂伸长率降低，说明通过葡萄糖改性可提 高改性聚氨酯胶膜的综合性能。 [关键词]水性聚氨酯微乳液；葡萄糖；改性聚氨酯胶膜 [文章编号]1000—8144(2013)09—0979—05 [中图分类号]TQ 630．4 [文献标志码]A Preparation and Properties of Waterborne Polyurethane Microemulsions Modified by Glucose and Their Films WangLei ，LaiXiaojuan ，MaShaoyun (Key laboratory ofAuxiliary ChemistryTechnology for Chemical Industry，Ministry of Education，Shaanxi University of Science Technology．Xi’an Shaanxi 7 1 002 1．China；2．Oilfield Chemical Research and Development Center ofYanchang Oilfield Fengyuan Enterprise General Company，Yah’an Shaanxi 716000，China) J Abstract J A series of modified waterborne polyurethane microemulsions and their solidified films were prepared with glucose as the crosslinker．The morphology of the modified polyurethane microemulsions。as wel1 as the structure。therma1 stability，mechanical properties and medium resistance of the modified polyurethane films were characterized by means of TEM，FTIR．XRD and TGA．The results indicated that glucose was introduced into polyurethane by the reaction between the hydroxyl of glucose and the—NCO group of polyurethane．With