Ti-USY催化剂光催化氧化汽油脱硫-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 · 582· PETR0CHEMICAL TECHN0L0GY 2014年第43卷第5期 Ti—USY催化剂光催化氧化汽油脱硫 范 立，沈 健 (辽宁石油化工大学 石化学院，辽宁 抚顺 113001) [摘要]以钛酸四正丁酯为钛源，采用浸渍法制备了固载TiO 的超稳USY分子筛(Ti—USY)催化剂，通过XRD，FTIR，TG— DTA，uV—Vis等方法对催化剂进行了表征。在紫外光照射下，以噻吩模拟汽油为原料，进行了光催化氧化脱硫实验，考察了 Ti—USY催化剂的焙烧温度、TiO：负载量对脱硫率的影响；并以催化裂化汽油为原料，考察了Ti—USY催化剂的再生及重复使 用性能。实验结果表明，在焙烧温度500 、TiO 负载量为15％(W)的条件下，可得到高度分散的锐钛矿型Ti—USY催化剂， 该催化剂具有较高的光催化活性，在最佳反应条件下，模拟汽油脱硫率可达84．1％；该催化剂经过7次再生重复使用，催化裂 化汽油脱硫率仍达57％以上，可满足国Ⅳ汽油硫含量标准。 [关键词]USY分子筛；Ti—USY催化剂；光催化氧化；汽油脱硫 [文章编号]1000—8144(2014)05—0582—05 [中图分类号]TQ426．95 [文献标志码]A Desulfuration of Gasoline by Photocatalytic Oxidation over Ti-—USY Catalyst Fan Li，Shen Jian (College ofPetrochemical Technology，Liaoning Shihua University，Fushun Liaoning 113001，China) l Abstract J TiO2-USY zeolite(Ti—USY)photocatalysts were prepared by impregnation using tetrabutyl titanate as titanium source and characterized by means of XRD．FTIR．TG．D and U S The performances of Ti—USY in the desulfurization of simulated gasoline with thiophene by photocatalytic oxidation under UV irradiation were studied．The effects of calcination temperature of Ti．USY and TiO， loading on the desulfurization rate were investigated．The results indicated that highly disperse anatase type Ti—USY catalyst could be attained under the conditions of calcination temperature of 500 oC and TiO，loading of 1 5％(w1．Under suitable conditions，the desulfurization rate of the simulated gasoline over the catalyst could reach 84．1％．After the catalyst was reused se