丁烯歧化制丙烯用负载型铼基催化剂-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2010年第39卷第2期 P]巳TROCHEMICAL TECHNoLOGY ·l5l· 丁烯歧化制丙烯用负载型铼基催化剂 袁桂梅，王海涛，陈胜利，桑 磊，马蕊英 (中国石油大学(IE京)重质油国家重点实验室，北京 102249) [摘要]采用浸渍法制备了不同Re2O7负载量的Re207／AI2O3催化剂，采用XRD、XRF、低温氮吸附一脱附、NH3一TPD、Fr 和 H2一TPR对催化剂进行了表征。表征结果显示，AI2O3载体负载Re2O7后在载体表面形成了新的活性物种；随Re2O 负载量的 增加，Re O7／AI O 催化剂的BET比表面积和孔体积减小，酸性增强；焙烧过程中Re2O7是否升华与载体的比表面积有关， Re O，单层分散阈值随载体比表面积的增大而增大。考察了Re2O，／A12O3催化剂催化丁烯歧化制丙烯的反应性能。实验结果表 明，Re，O，负载量对歧化反应的选择性影响不大，在，，z(2一丁烯)： (1一丁烯)=1．2、重时空速1 h。。、60 oC、2 MPa的条件下，选 择性始终保持在85％以上；丁烯转化率随Re2O 负载量的增加明显增大，最高达50％，接近平衡转化率；当Re2O，负载量由5％ 增至20％时，催化剂的寿命明显延长。 关键词]铼基催化剂；氧化铝载体；丁烯；歧化；丙烯 [文章编号]1000—8144(2010)02—0151—06 [中图分类号]TQ 426．82 [文献标识码]A Re2 O7／AI2 O3 Catalysts Used in Producing Propylene by Butene Metathesis Yuan Guimei，Wang Haitao，Chen Shengli，Sang Lei，Ma Ruiying (State Key Laboratory of Heavy Oil Processing，China University of Petroleum—Beijing，Beijing 102249，China) [Abstract]Re2 07／A12 03 catalysts with different Re2 O7 loadings were prepared through impregnation and characterized by means of XRD，XRF，N2 adsorption—desorpfion，NH3-TPD，FrIR and H2-TPR． Results showed that active component on the A12O3 support surface was formed．With increasing of Re2 O7 loading，BET surface area and pore volume of the catalyst decreased，but its acidity was enhanced．Loss of Re2O7 in the catalyst in calcination process was related to the specific surface area of Al2 03 support．Threshold value of Re2 O7 loading increased with the increasing of specific surface area Of 2 O3 support．The catalytic properties of Re2 O7／A12 03 were evaluated in metathesis