TiCl4处理次数对TiCl4／MgCl2催化剂性能的影响-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2010年第39卷第1期 PETR0CHEMICAL TeCHN0L0GY ·57· TiCI4处理次数对TiCl4／MgCl2催化剂性能的影响 高富堂 。，夏先知 ，毛炳权 (1．北京化工大学 材料科学与工程学院，北京 100029；2．中国：百油化工股份有限公司 北京化工研究院，北京 100013) [摘要]根据聚丙烯DQ催化剂制备工艺，改变TiC14的处理次数制备了一系列TiC14／MgC12球形催化剂。用分光光度计、比表面 及孔径分析仪、SEM、FTIR、XPS等技术对催化剂进行了表征，考察了催化剂的活性和立体定向性。实验结果表明，随TiCI 处理 次数的增加，催化剂中Tf含量先迅速降低后缓慢下降；活性、等规度和比表面积均呈先大幅增加后趋于稳定的趋势；TiCI 处理一 次时合成的催化剂的表面较光滑，出现小的裂纹，TiC1 多次处理得到的催化剂表面出现大的裂缝；随TiC1 处理次数的增加，酯在 催化剂中的配位强度增加，Tj 2p 结合能降低，TiC1 处理次数超过3次时合成的催化剂的Ti 2p 结合能趋于稳定；Ti 2p3，2结合 能越低，酯的配位强度越大，活性和等规度越高。 [关键词]四氯化钛处理次数；Ziegler～Natta催化剂；球形催化剂；聚丙烯 [文章编号]1000—8144(2010)01—0057—04 [中图分类号]TQ426．82 [文献标识码]A Effects of TiCI4-Treated Times on Properties of Polypropylene TiCI4／MgCl2 Catalyst Gao Futang ，Xia Xianzhi ，Mao Bingquan ’ (1．College of Materials Science and Engineering，Beijing UnNersity of Chemical Technology，Beijing 100029，China 2．Beijing Research Institute of Chemical Industry，SINOPEC，Beijing 100013，China) [Abstract] According to DQ catalyst preparation process，a few TiC14／MgC12 spherical catalysts were prepared by changing TiC14-treated times．The catalysts were characterized by means of spectrophotometer， surface area and pore size analyzer，SEM，FHR and XPS．Activities and stereospecificities of the catalysts were investigated．With the increase of TiCI4-treated times，titanium contents of the catalysts first decreased rapidly and then slowly；activities，stereospecificities and specific surface area of the catalysts first greatly increased and tended later to be stable．The：catalyst surface was smooth and there were some