水热体系下新型层状UZM-8沸石的合成-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2011年第40卷第1期 唧 ROCHEMICAL TECHN0LOGY ·29· 水热体系下新型层状UZM一8沸石的合成 钱 斌，陈 燕，郑均林，孔德金 (中国石化 上海石油化工研究院，上海201208) [摘要]水热体系下合成了新型层状UZM一8沸石，采用”C交叉极化魔角旋转核磁共振(”C CP MAS NMR)谱研究了该体系下 二甲基二乙基氢氧化铵(DEDMAOH)的模板导向作用。研究结果表明，DEDMA 与沸石发生较强的相互作用，处于沸石的不同 化学环境中，起到了较强的模板导向作用。采用XRD和SEM方法对合成的UZM一8沸石进行了表征，考察了晶种和Na 对 UZM一8沸石的形成及结构的影响。实验结：秉表明，当n(DEDMA )：n(SiO，)0．3时，合成体系中UZM一8沸石无法自发结 晶，而当体系中存在Na 和晶种时，n(DEDMA )：n(SiO，)=0．1时仍可合成出UZM一8沸石，且合成产物UZM一8沸石的结晶 度提高，晶化时间缩短。 [关键词]UZM一8；层状沸石；水热合成；晶种；模板；催化材料 [文章编号]1000—8144(2011)01—0029—05 [中图分类号]TQ 424．25 [文献标识码]A Synthesis of UZM --8 Zeolite in Hydrothermal System Qian Bin，Chen Yan，Zheng Junlin，Kong Dejin (Shanghm Research Institute of Petrochemical Technology，SINOPEC，Shanghm 201208，China) 』Abstract 1 Novel layered UZM．8 zeolites were hydrothermally synthesized using diethyldimethyl— ammonium hydroxide(DEDMAOH)as a template．The strong interactions between the DEDMA and the zeolites were found by means of”C CP MAS NMR， which indicated the structure—directing function of the template for forming the UZM一8 zeolites． The resultant UZM一8 zeolites were characterized by means of XRD and SEM．Effects of the crystal seeds and Na on formations and structures of the UZM一8 zeolites were investigated．The results indicated that the UZM一8 zeolites could not be crystallized spontaneously when (DEDMA )： (SiO，)0．3．As bom Na and the crystal seeds existed in the synthesis system． the UZM．8 zeolites could be obtained even when (DEDMA )：n(Si0，)=0．1．Meanwhile．the crystallinities of the resultant UZM．8 zeolites rose and their crystallization periods shortened． [Ke