丙烷脱氢分离工艺的模拟与分析-学兔兔 www.xuetutu.com.pdfVIP

学兔兔 石 油 化 工 2015年第44卷第4期 PETROCHEMICAL TECHNOLOGY ·421· 丙烷脱氢分离工艺的模拟与分析 张 琦，隋志军，顾雄毅，周兴贵 (华东理工大学化学工程联合国家重点实验室，上海200237) [摘要]对300 kt／a丙烷脱氢装置的分离工艺流程采用Aspen Plus化工流程模拟软件进行模拟，通过比较不同操作条件下各单 元的模拟结果并分析各单元的能耗，确定急冷、压缩、深冷分离、脱C 、丙炔加氢和丙烯精馏等单元的操作条件，考察了在已 确定的操作条件下各分离单元的能耗。模拟结果表明，丙烷脱氢分离工艺主要操作条件为：压缩机出口压力1．10 MPa、深冷分 离温度_95℃、脱乙烷塔操作压力0．90 MPa、丙烯精馏塔顶操作压力0．75 MPa，使用热泵精馏塔；丙烷脱氢分离工艺中，主要 耗能单元是压缩和深冷分离单元及丙烯精馏单元，其能耗分别占分离工艺总能耗的50．4％和35．6％，脱c：单元和急冷单元的 能耗分别占总能耗的11．8％和2．2％。 [关键词]丙烷脱氢；分离工艺；丙烯；级联制冷；热泵精馏 [文章编号]1000—8144(2015)04—0421—08 [中图分类号]TQ 021．8 [文献标志码]A Simulation and Analysis of Separation Process in Propane DehydrOgenatiOn to Propylene Zhang Oi，Sui Zhijun，Gu Xiongyi，Zhou Xingui (State Key Laboratory of Chemical Engineering，East China University of Science and Technology，Shanghai 200237，China) [Abstract]The separation process in a 300 kt／a plant for the dehydrogenation of propane to propy— lene was simulated by means of Aspen Plus software．The simulation results for quenching unit，com— pression unit，cryogenic separation unit，deethanizer unit，propyne hydrogenation unit and propylene rectification unit，and the energy consumptions of the units were investigated to determine the operation parameters．It was showed that the main operation parameters for the separation process were compre— ssor discharge pressure 1．10 MPa．cryogenic separation temperature-95℃，deethanizer operating pre- ssure 0．90 MPa and propylene rectification tower operating pressure 0．75 MPa with heat pump disti— llation．In the separation process，the main e