_混合醇醇解RPET制备不饱和聚酯树脂的研究.pdfVIP

第28 卷第2 期 天 津 化 工 Vol.28 No.2 2014 年3 月 Tianjin Chemical Industry Mar.2014 ·科技论文· 混合醇醇解RPET 制备不饱和聚酯树脂的研究 1,2 1 1 1* 刘亚春 ，孙帅帅 ，管山 ，郭玉高 天津工业大学环境与化学工程学院，天津 ； 中国石油化工股份有限公司润滑油公司天津分公司，天津 (1 300387 2 300480) 摘要：本文以醋酸锌为催化剂，利用混合醇取代二元醇作为醇解剂对回收聚对苯二甲酸乙二醇酯塑 料降解，得到的醇解产物与酸酐进一步缩合聚合，以苯乙烯作为稀释剂，制得不饱和聚酯树脂。该方 法具有工艺简单、成本低廉、操作简便、绿色环保、经济效益好等特点，得到的不饱和聚酯树脂性能 稳定，使用性能良好。 关键词：混合醇；不饱和聚酯；聚对苯二甲酸乙二醇酯 doi: 10.3969/j.issn.1008-1267.2014.02.002 中图分类号：TQ323.4 文献标志码：A 文章编号：1008-1267 （2014）02-0005-04 Preparation of unsaturated polyester resins from mixed alcohols decomposition of recycled poly(ethylene terephthalate) LIU Ya-chun 1,2, SUN Shuai-shuai 1, GUAN Shan 1, GUO Yu-gao 1* (1 School of Environmental and Chemical Engineering, Tianjin Polytechnic University Tianjin, 300387; 2 Tianjin Branch, Lubricant Company, Sinopec corp., Tianjin, 300480) Abstract: In this paper, with zinc acetate performed as catalyst, we used mixed alcohols as alcoholysis agent to decompose recycled poly (ethylene terephthalate) (RPET). After that, obtained alcoholysis products reacted with maleic anhydride and phthalic anhydride ，and then the styrene was added in order to dilute the resin and became cross-linking. Finally，we obtained the unsaturated polyester resin. The synthesis process and optimum formula is simple, cheap, environmental friendly and economical, etc. The final product is stable and has a good intensity. Key words: mixed alcohols; unsaturated polyester resin; PET; poly(ethylene terephthalate) 学法。物理法相对比较简单，主要是通