卫鲁蓝晶石的特性研究.PDF

卫鲁蓝晶石的特性研究 1 1 1 2 2 韩丽营 沈毅 李红生 王兴国 陈发策 (1 河北联合大学材料科学与工程学院 河北唐山 063009; 2 邢台兴国蓝晶石制造有限公司 河北邢台 054000) 摘要 本实验所用原料来自于卫鲁蓝晶石精矿。将卫鲁蓝晶石原料湿磨后成型并进行烧结。利用湿化学方 法、X 射线衍射分析仪（XRD ）、粒度分析仪和扫描电子显微镜（SEM ）对卫鲁蓝晶石的化学成分，矿物 o 组成、湿磨后粒径和微观形貌进行了表征，并考察了其烧结性能。研究表明：在 1100 C 左右就开始了蓝 o 晶石向莫来石的转化过程，在 1250 C 时，可以在SEM 照片中明显的看到一次莫来石化形成的鳞片状莫来 石。 关键词 卫鲁蓝晶石，莫来石，烧结性能 Research on Characteristices of Weilu Kyanite HAN Liying1 SHEN Yi1 LI Hongsheng1 WANG Xingguo2 CHEN Face2 (1 College of Material Science and Engineering Heibei United University Hebei Tangshan 063009; 2 Xingtai Xing Guo Manufacturing Company Ltd Hebei Xingtai 054000) Abstract The raw materials used in this experiment came from the kyanite mine of Weilu village, Hebei. In this paper, raw kyanite were grounded with water, then shaped and sintered for the next research. The chemical composition of kyanite was tested by chemical methods; as for the mineral composition, grain size after grounded and microstructure were analyzed with X-ray diffraction, laser particle size analyzer and SEM instruments. Beyond that, sintering properties were also examined. The study demonstrated: the transforming from kyanite to mullite began with 1100 tempreture, when tempreture reached 1250 ℃, obvious scaly structure mullite could be seen in the SEM pictures. Key words Weilu kyanite; mullite; sintering property 1 前言 蓝晶石是一种新型耐火材料，成分为 Al [SiO ]O ，属于高铝岛状结构硅 2 4 酸盐矿物，三斜晶系，晶体呈扁平的板条状，有时呈放射状集合体，与红柱 石、矽线石成同质多象，具有完全和中等的两组解理。颜色通常呈蓝色、带 蓝的白色或青色。硬度有明显的异向性，故又名二硬石。由蓝晶石煅烧生成 的莫来石，具有高温稳定性、低膨胀性及良好的耐火性和高温下的高负荷能 力。由于其膨胀效应可以抵消某些材料的收缩，使产品具有高温体积变化小、 热稳定性好、耐抗渣和抗磨，不需煅烧出料直接使用，能适应快速烧成，节约