玉门稠油组分特征及其对结蜡行为的影响.pdfVIP

第42卷 第2期 燃摇 料摇 化摇 学摇 学摇 报 Vol.42 No.2 2014年2月 Journal of Fuel Chemistry and Technology Feb. 2014 文章编号:0253鄄2409(2014)02鄄0187鄄06 玉门稠油组分特征及其对结蜡行为的影响 苏慧君,陈摇 刚,栗摇 菁,李小龙,张摇 洁 (西安石油大学 化学化工学院,陕西 西安摇 710065) 摘摇 要:为了研究稠油不同组分的特征及其相互作用,利用柱层色谱分离法、傅里叶红外光谱、差示扫描量热法(DSC)和偏光 显微分析等表征方法及手段,对采自玉门油田的稠油样品进行了组分分离、分析,并对饱和烃组分结蜡行为的影响进行了研 究。 结果表明,稠油各组分相互作用可以有效抑制蜡晶的析出。 饱和烃组分(A )中分别加入其他不同极性组分后,其结蜡行 1 为与原油原始状态差异较大;A 的析蜡点、析蜡峰温和析蜡量均有所降低。 偏光显微分析发现胶质沥青质组分使A 冷却结 1 1 晶时的蜡晶颗粒数增多,尺寸相对减小,可以减弱蜡晶之间的联结强度,削弱蜡晶缔合而形成大块蜡晶聚集体的倾向。 关键字:稠油;饱和烃;胶质;沥青质;结蜡 中图分类号:TE345摇 摇 文献标识码:A Characteristics of Yumen heavy oil components and its effect on wax deposition behavior SU Hui鄄jun,CHEN Gang,LI Jing,LI Xiao鄄long,ZHANG Jie (College of Chemistry and ChemicalEngineering,Xi爷an Shiyou University,Xi爷an摇 710065,China) Abstract:The characteristics of components of heavy oil,their interactions and effects on the wax deposition behavior of heavy oil from Yumen oil field were studied by using chromatogram separation,Fourier transform infrared spectroscopy (FT鄄IR),differential scanning calorimetry (DSC) and optical microscope. The results indicate that the interaction between the components can inhibit the precipitation of wax crystal effectively. The behaviors of A with different polarity componentsadded are quite different from that of the heavy oil. The wax 1 -appearing temperature,the peak temperature of wax鄄precipitation and the percentage of precipitated wax are decreased. The optical microscopeanalysisshowsthat theaddition ofresin andasphaltenetoA can increasethe