小龙潭褐煤加氢液化及其重质产物结构表征.pdfVIP

第43卷 第5期 燃摇 料摇 化摇 学摇 学摇 报 Vol.43 No.5 2015年5月 Journal of Fuel Chemistry and Technology May2015 文章编号:0253鄄2409(2015)05鄄0560鄄07 小龙潭褐煤加氢液化及其重质产物结构表征 王知彩,水恒福,潘春秀,任世彪,康士刚,雷智平 (安徽工业大学 化学与化工学院安徽省煤洁净转化与利用重点实验室,安徽 马鞍山摇 243002) 摘摇 要:研究了小龙潭(XLT)褐煤直接加氢液化性能,并利用元素分析、红外光谱和荧光光谱法对液化重质产物沥青烯(AS) 和前沥青烯(PA)结构进行了分析表征。 结果表明,XLT褐煤液化活性高,FeS催化415 益时液化转化率最高达到89.6%,其 液化过程主要是煤大分子结构热解并脱氧。 所得AS和PA 的芳环结构单元类似于原煤,氧主要以羟基和芳香酮羰基形式存 在。 PA具有“列岛冶(archipelago)式大分子结构特征,芳香结构含量明显大于AS。 THF溶液中,PA缔合作用显著强于AS,尤 其在稀溶液中PA存在一定的分子内缔合。 较高温度下所得PA和AS 中芳香结构含量高,缔合作用强。 关键词:小龙潭褐煤;加氢液化;结构表征;重质产物;缔合作用 中图分类号:O657.3摇 摇 文献标识码:A Hydro鄄liquefaction of Xiaolongtan lignite and structural characterization of its heavy products WANG Zhi鄄cai,SHUI Heng鄄fu,PAN Chun鄄xiu,REN Shi鄄biao,KANG Shi鄄gang,LEI Zhi鄄ping (School of Chemistry and ChemicalEngineering, Anhui University of Technology,AnhuiKey Laboratory of Clean Coal Conversion Utilization,Ma 爷anshan摇 243002,China) Abstract:The hydro鄄liquefaction properties of Xiaolongtan (XLT) lignite were investigated,and structures of the heavy products, including asphaltene (AS) and preasphaltene (PA) were characterized by elemental analysis,FT鄄IR and fluorescence spectroscopy. The results indicate that XLT lignite shows high liquefaction reactivity,and its conversion catalyzed by FeS at 415 益 is 89.6%. During hydro鄄liquefaction,the macro鄄 molecule ofcoalarepyrolyzedanddeoxygenized. Thearomatic structureunitsinASandPAare similar tothose in the coal. Hydroxyland carbonylin the form ofaromaticketonearemain oxygen containing groupsin ASand PA. The relative content of aromatic structure of PA,dominant in the archipelago molecular architecture,is obviously higher than that of AS. In THF solvent, PA shows significantly stronger aggregation than AS, especia