从葡萄糖变石墨烯.pdfVIP

Angewandte Chemie DOI: 10.1002/anie.201203207 Nanomaterials Synthesis of Monolayer-Patched Graphene from Glucose** Xin-Hao Li,* Simon Kurasch, Ute Kaiser, and Markus Antonietti* The extraordinary electronic and mechanical properties[1, 2] of standing graphene with a yield of 28–60% (calculated based graphene have stimulated intense research on developing on added carbon from glucose). simple methods for the large-scale synthesis of graphene.[1–9] The overall formation process is depicted in Figure 1: High-quality large-area graphene films prepared by the Thermal condensation of DCDA creates a layered carbon chemical vapor deposition of various carbon-containing molecules on arbitrary substrates could meet the require- ments of large-area electronic applications.[3–7] For the industrial production of conductive graphene powder on the ton scale,[3, 9, 11–13] the chemical exfoliation of graphite minerals still remains the main manufacturing path.[3,8–10] On the other hand, the exclusive two-dimensional polymerization of gra- phene-like structures from simple monomers still presents a challenge for carbon chemists.[14–19] Further fine-tuning of the Fermi level of graphene by doping offers a way to control the electronic structure of carbonaceous materials[6,20–23] and is of major interest for their application in electronics,