2-氨基对苯二酸铒配合物的合成、结构及性质表征.pdfVIP

2014 年第15 期 广东化工 . 5. 第41 卷总第281 期 www.gdchem .com 2-氨基对苯二酸饵配合物的合成、结构及性质表征 张肉，赵兵，谭爱东，黄绍春，刘利 [t部l 要]利用水热合成自组装成具有三维空间结构的新颖配仪聚合物. Er1(atpa )J(DMF )2(H20h (DMF=NN-_ .rp iirr ð先胶)(1 ). 并对Jti挂行了 吁 品结构测定、红外光i籍、炎光光谱及热1区分析. x-射线P品衍射击生据表明. 1七介物 1 隶属三7i，\， 系• P-J 空间群. a=8.1437(16)Â. b= 10.217(2) Â. c = 11 .580(2) 人α= 114.728(3)0.13 = 99.521(3}0.1 = 98.940(3)0. V = 835.7 Â飞 z = 1 ， 该化合物涵过双核念成中心形成穿~di 网络结构. [关键词J2-$.O在对苯 ;酸: 肉已仿-聚合物;晶体结构: - UE [叶叶钊分类号)0614.344 [ 文献品J;l只码JA [文 结编辛苦)1007-1865(2014)15-0005.03 Synthesis, Structure Characterization and properties of Porous Erbium(III) Coordination Polymers with 2-aminoterephthalic acid Zhang Yun. Zhao Bin, Tan Aidong, Huang Shaochun, Liu Li (College of Materia1s Science and Engineering, Huaqiao University, Xiamen 361021 , China) Abstract: Thc Erz(atpa)J(DMF)z(HzO)z (DMF = N,N-Dimethylfonnamide) with 山时dimensional space structure has been self-assembled by hydro由ennal synthesis, and the single-crystal srructure of Er2(arpa}J(DMF)2(HzO)z was measured , the infrared spectros∞py， fluorescence sp饵troscopy and thermogravimetric analysis were meas町创 as wel l. The data of X-ray single crystal dif击action showed that the compound has a network srructure which is interpenetrating. The crystallographic 归ramete罚部 follow: Trigonal system, P-I space group, a = 8.1437(1 6) 人b = 10.217(2) Å , c = 11.580(2} A, a = 114.728(3)0, 13 = 99.521(3)0. 1 = J 98.940(3沪， v = 835.7 A , Z = 1.