SiO2杉木粉复合材料的制备和表征.pdfVIP

豆合材料营报 第 24 番第3 期 6 月 2007 年 ..ç;jc);a; JiaJ;，阴心aø 电附中灿品仙飞!UYIJi:;伪 Vo l. 24 No. 3 June 2007 文章编号: 1000-3851(2007) 03 0084 … 05 Si0 /杉木粉复合材料的制备和表征 2 徐啥，:(.钦钩\锦疙宏，豆鹏 (合肥工业大学化工学院，合肥 230009) 摘 要: 以人工林杉木粉为原料和正硅酸L醋CTEOS) 为无机前驱体，依据溶剂热法反应原理，采用溶胶凝胶 的方法制备了 Si0 /*材复合材料。通过红外光谱分析CFTIR) 、 X 射线衍射分析(XRD) 、热失熏分析CTGA) 、扫 2 描电子显微镜分析的EM)等方法，研究了该复合材料的结构和性能。研究结果表明，使用这种方法，木材的增草 率显著提高。木材巾的经基与正硅酸乙酣水解盾的琵基发生了缩合反应，体系中存在 Sí…O-C 交联网络，微观 上形成了纳米网络结构。水质纤维素的结晶被破坏，结晶度从 75.37%(纯木粉)下降到 37.42%( 木材增重率为 78% 的复合体系)。交联网络的形成显著提高了该材料的耐热性能，使失重 10% 时的热分解温度从 270 C (纯木 粉)提高到 409C 。 关键词: 木材; SiO ; 耐热性 z 中阁分类号: TB332 文献标i只码 :A Preparation and characterization of Si02 / wood hybrid materials XU Feng , SHI Tiejun* , ZHANG Kehong , WANG Peng (School of Chernical Engíneeríng , Hefei Uníversíty of Technology , Hefei 230009 , China) Abstract: SiOzlwood hybrid rnaterials were prepared by the rnethod of 501 … gel using TEOS as inorganic rn巳diurn and chína fir as raw rnaterials , according to the principle of solvotherrnal method. The structure and property of the hybrid rnaterials were analyzed by FTIR , XRD , TGA and SEM. The results 5how that the WPG (weight perc巳nt 日ain) of the wood gets a rnarked irnprovernent and the hydroxyl groups frorn the hydrolysis of TEOS reacted with the hydroxyl groups of the wood. In SEM analysis , the network whose size is in nanoscale is found , which resulted frorn the coagulation of Si-O… C network. And in XRD analysis , the crystalline phase of ligno