二维沸石及其在大分子催化转化领域的研究进展.pdf

大学化学(Daxue Huaxue) February Univ. Chem. 2017, 32 (2), 1－8 1 ∙今日化学∙ doi: 10.3866/PKU.DXHX201609009 二维沸石及其在大分子催化转化领域的研究进展 黄阳环 张宏斌 唐 颐* (复旦大学化学系，上海200433) 摘要：与三维结构沸石不同，二维沸石由于其更开放的孔道结构、更大的比表面积、更易暴露的酸性位 点，在大分子和扩散限制催化领域显示了特殊优势。通过各种合成和后处理方法，能够调控二维沸石及 其衍生材料的孔道种类、大小与分布，从而适用于不同的催化过程。本文综述了近年来二维沸石的合成 与应用进展。 关键词：二维沸石；孔道；水热合成；后处理 中图分类号：G64 ；O6 Progress of Two-Dimensional Zeolites and Their Applications in Bulky Molecule Catalytic Conversion HUANG Yang-Huan ZHANG Hong-Bin TANG Yi* (Department of Chemistry, Fudan University, Shanghai 200433, P. R. China) Abstract: Compared with three-dimensional zeolites, two-dimensional zeolites possess the more open skeleton structure, larger specific surface area and more exposed acid sites, resulting in special advantages in bulky molecule catalysis or diffusion-limited catalysis. Through diverse direct synthesis methods or post- processing methods, pore species, pore size and pore distribution of two-dimensional zeolites and derived materials can be adjusted to be suited for various catalysis processes. Here, we summarize the recent progress of two-dimensional zeolites including syntheses and applications. Key Words: Two-dimensional zeolites; Pore; Hydrothermal synthesis; Post-processing 沸石(zeolite)是一类具有规整微孔结构的铝硅酸盐晶体材料，其微孔结构可以在亚纳米甚至纳米 [1] 尺度实现分子的 “筛分”，实现择形分离、吸附或催化转化，因此形象地称为 “分子筛” 。此外沸 石具有优良的热稳定性和水热稳定性以及组分可调性，成为工业催化中长盛不衰的固体酸催化材料。