新型含双长链和苄基的有机硅季铵盐的合成.pdfVIP

学兔兔 2014年第22卷 合成化学 Vo1．22，2014 第6期，797～799 Chinese Journal of Synthetic Chemistry No．6，797～799 · 快递论文 · 新型含双长链和苄基的有机硅季铵盐的合成 丁寒卫，郭文涛，薛永强，崔子祥 (太原理工大学化学化工学院，山西太原 030024) 摘要：以双十二胺(1)为原料，与氯化苄经取代反应制得中间体苄基双十二胺(2)；2与 ．氯丙基三甲氧基硅 烷(3)经季铵化反应合成了一种新型的含双长链和苄基的有机硅季铵盐(4)，其结构经uV．Vis和Fr．IR表征。 通过正交实验L9(3 )优化了2和4的反应条件。合成2的最佳工艺条件为：以乙腈为溶剂，1 5 mmo]， n(1)：n(BnC1)=1．0：1．2，回流反应20 h，收率80．4％。合成4的最佳工艺条件为：以乙二醇为溶剂，2 5 mmol，n(2)：n(3)=1．0：1．6，于11O℃密闭反应80 h，收率57．8％。 关 键 词：双长链；有机硅季铵盐；合成 中图分类号：0627．41；TQ．423．12 文献标识码：A 文章编号：1005．1511(2014)064)797-03 Synthesis of a Novel Organosilicon Quaternary Ammonium Salt Containing Double Long—chain Alkyls and Benzyl DING Han—wei， GUO Wen-tao， XUE Yong-qiang， CUI Zi-xiang (College of Chemistry and Chemical Engineering，Taiyuan ullivers of Technology，Taiyuan 030024，China) Abstract：The intermediate，N-benzyldidodecylamine(2)，was obmined by substitution reaetion of didodecylamine(1)with benzyl chloride．A novel organosilicon quaternary ammonium salt(4)contai． ning double long—chain alkyls and benzyl was synthesized by quaternization reaction of 2 with y．chlo— ropropyltrimethoxysilane(3)．The structures were characterized by UV—Vis and FT—IR．The synthesis conditions of 2 and 4 were optimized through orthogonal experiment (3 )．The results showed that the optimized conditions were as fo~ows respectively：acetonitrile was the solvent，1 was 5 mmo1． rt(1)：rt(benzyl chloride)=1．0：I．2，reflux for 20 h，the yield of 2 was 80．4％；glycol was the solvent，2 was 5 mmol，n(2)：n(3)=1．0：1．6，the yield of 4 was 57．8％at 110 c【=for 80 h． Keywords：double long-chain alkyls；organic silicone quaternary ammonium salt；synthe