环氧氯丙烷改性PAMAM的制备及其在染整中的应用.pdfVIP

Abstract This paper mainly studied the modification of PAMAM dendrimer and its applicationinfiber. This experiment used divergent method to synthesize the 2.0 generation PAMAM. And Epoxy chloropropane as raw materials to modify the 2.0 generation PAMAM dendrimertobemodifiedPAMAM dendrimer.Theresult showedthatthematerialsratio of PAMAM and Epoxy chloroproane was 1:12, and then reacted for 5h under the temperature of 55 , then debase the temperature to 30 and reacted for 2h, the ℃ ℃ thicknessofKOHwas50%andtheyieldwas70%. The cotton fabric was treated with 10g/Lof the modified PAMAM and 40g/L of catalyst NaOH, baked at 130℃ for 75s, the results showed that the recovery angle increased by 17.5%, while the warp strength retention was over 90%, and the white contentkeepsover85.1%,andthewashingfastnesswaswell. In order to improve the dye-ability of cotton fabric with reactive dyes, the cotton fabricwaspretreated withmodifiedPAMAM.ThedyedmodifiedPAMAMcottonfabric exhibited the similar K/S values and washing fastness and rubbing fastness in salt-free dyeing.Fouriertransforminfraredspectrophotometryindicatedthatthe-OHgroupofthe cotton fibers had reacted with the modified PAMAM. The results showed that fabric treatedwith 10g/LofmodifiedPAMAMand40g/LofNaOH,andreacted5minunderthe temperature of 60℃. The dyed cotton fabric with reactive dyes in salt-free dyeing displayedbettercolorstrength,washingfastnessandrubbingfastness. Keywords:modification dendrimer crease-resist;salt-freedyeing 目 录 第一章 绪 论1 1.1 树枝状大分子概述1 1.1.1 树状大分子的结构2 组成2 结构的完整性2 几何对称性2 分子内的空腔结构2 端基官能团3 相对分子质量的可控性3 分子量的分散性3 1.1.2 树枝状大分子的性能特点3 流动性3 溶解性4 黏度4 成膜性4 多功能性4 其他性质4 1.2 树枝状大分子的制备方法5 1.2.1 发散型合成法5 1.2.2 收敛型合成法5 1.2.3 发散收敛共用法6 1.2.4 固相合成法6 1.2.5 金属配位法6 1.3 树枝状大分子的应用6 1.3.1 在医学方面的