聚丙烯酸酯分散液晶的光聚合动力学及其薄膜的电光特性.pdfVIP

华 中 科 技 大 学 硕 士 学 位 论 文 obviously with the reaction time, and it can be indicated some traces of dark reaction after the illumination turned off when the reaction time between 60s and 180s. 2. The phase diagram of the acrylate monomer/LC mixture before cured and the degree of phase separation after cured was studied by differential scanning calorimetry (DSC). The results showed that the phase separation temperatures of the mixture increase with the LC content. And the LC solubility limit β in the polyacrylate is 0.29 at room temperature. 3. With the content of liquid crystal increasing, both the threshold voltage and saturation voltage of the composite film tend to decrease. However, the two type of voltage increase with the average functionality. Surfactant reduces the anchoring energy and the phase separation of the composites, which results in the threshold voltage being lowered slightly. 4. With POSS content increasing, the Rpmax of polyacrylate dispersed liquid crystal composites tends to decrease and liquid crystals droplet becomes small. The POSS enhances the thermal stability of the composites, while the rigid cage-like structure of POSS increases their switching voltages. Key words ：Polyacrylate dispersed liquid crystals, Photopolymerization kinetics, Phase separation, Electro-optic properties, POSS IV 独创性声明 本人声明所呈交的学位论文是我个人在导师指导下进行的研究工作及取得的研 究成果。尽我所知，除文中已经标明引用的内容外，本论文不包含任何其他个人或 集体已经发表或撰写过的研究成果。对本文的研究做出贡献的个人和集体，均已在