基于纳米羟基磷灰石溶胶的nHAPA66复合粉体制备与表征.pdfVIP

第 25 卷第 2 期 无机化学学报 VoJ. 25 No.2 236向242 2ω9 年 2 月 CHINESE JOU民NAL OF INORGANIC CHEMISTRY 基于纳米经基磷灰石溶胶的 nHAlPA66 复合粉体制衡与表征 沈荣臻陈氏芳*刘德宝谭牢牢 (天津理工大学材料科学与工程学院，天津 3ω191) 摘要:本文开发了一种新的制备纳米烧基磷灰石(nHA)/聚航股 66(PA66)复合材料的方法。先用明胶包穰 nHA 棒状颗粒，再将其 制备成以 N， N-二甲基乙股股和甘油的混合液为静剂的稳定溶胶。当 nHA 溶胶与 PA66 熔液海合时，相同的毗胶基因保证了一 者之间良好的共晦相容性，成功和l 备了 nHAlPA66 复合材料。X 射线衍射(XR川、傅立叶红外光谱分析(FiIR) ，透射电镜(四川，扫 描电镜能谐分析(SEM-EDS)以及慈热分析(DTA)和热重分析(TG)等农征了产物的形貌、结构及成分分布。结果表明:明胶对 nHA 颗粒具有显著的化学包覆作用，使 nHA 熔胶与 PA66 榕液得以均匀混合，均匀分布在 PA66 基体巾，工者以氢键结合为…体。 关键词:起基磷灰石;溶胶;聚股股;复合材料;榕液媲合 中图分类号: 0613.62; TB333 文献标识码:A 文章编号: 1 ∞1 -4861(2∞9)02-0236-07 Preparation and Characterization of nHA!PA66 Composite ßased on the Hydroxyapatite Sol SHEN Rong…Zhen CHEN Min-Fang* LIU De.…Bao TAN Jun-Jun (仙。l 01Materials ScieTICe and Engineering, Tianjin University 01 Technology, TI叩ljin 3∞191) Abstract: This work developed a novel process for preparing nano hydroxyapatite (nHA)/polyamide66 (PA66) composite. 白le HA nanorods were coated by Gelatin first. and then dissolved them in the solvent mixed glycerol and N,N-dimethylacetamide. A stable sol of nHA was consequently prepared. Due to the Gelatin coated on the surface of nHA contains amide groups to be as the same as PA66 , they have good compatibility in the mixture of HA sol and PA66 solution, which resulted in synthesizing nHA/PA66 composite successfully. The morphology , structure and component analysis of composite have been studied using various techniques , such as X-ray diffraction (XRD), Fourier transform infrared spectros