溶胶凝胶法制备锂离子电池正极材料LiFePOlt4gt.pdf

有下降低。且随着掺杂量的增大，LiFeP04的颗粒也随之长大，颗粒大小不均，导致电 池放电容量进一步降低。 关键词： 锂离子电池，LiFeP04，溶胶凝胶法，表面活性剂，微观结构，电化学性能 Abstract as to LiFeP()．isconsidereda cathodematerialforlithi啪-ionbatteriesdueits promising meritssuch船low friendlinessand electrochemical cost,environmental capability,etc． good electron of is 10d0100cm2／s．The of However,theconductivityLiFeP04 just capacity islowat rate．Onthebaseofa ontheresearchandthe LiFeP04 hi曲discharge systematical of asacathodematerialoflithiumion Sol—Gelmethodis LiFeP04 development battery,a to LiFcP04 and and prepare by glycol勰solventLiOH，FeC204NH4H2P04鹪 adopted using resctantsinthis intheaimsof to LiFeP04 paper developing锄availabletechniqueprepare with ofthefabrication hi【ghproperties．m地effects parameters’includingsintering ofthe and tenaperaturas，pre-sinteringtemperaturegelprecursor,sinteringatmospheres Sul-fao∞active electrochemical additiononthemicrostmcmmand of reagent properties were rate of isincreased the LiFeP04 LiFeP04 investigated．Thehigh capacity byoptimizing fabrication technique． Themiaf0矧帅“血ll℃of differentfabrication was