纳米颗粒的制备及光谱性能研究.pdf

Ag@Si02纳米颗粒的制备和光谱性能研究／王蕊等 ·9· Ag@Si02纳米颗粒的制备和光谱性能研究* 王蕊，唐建国，王瑶，刘继完，黄林军，黄震 (青岛大学杂化材料研究所纤维材料与现代纺织国家重点实验室培育基地，青岛266071) 摘要 利用还原法制备纳米银溶胶，采用改进的St6ber法分别于乙醇和正丁醇溶剂中制备Ag@Si()2。透射 电镜(TEM)表明在乙醇溶剂中实现了包覆，X射线衍射(xJm)表明纳米银具有规则的面心立方结构，X射线光电予 能谱(Ⅺ)S)更Ij进一步表明银颗粒表面构筑了si()z壳层。壳层厚度对银溶驳的光谱性质有显著影响，紫外可见吸收 光谱表明最大吸收峰发生红移；荧光光谱表明si()2壳层的包覆使纳米银的激发和发射光谱强度降低。 关键词 Ag@si02si()2壳层紫外光谱荧光光谱 of Its on and StudyPreparationAg@Si02NanoparticlesopticalProperties WANG Yao，LIU Zhen Rui，TANG Jixian，HUANGLinjun，HUANG Jianguo，WANG (State NewFiberMaterialsandModemTextile-theBase，1nstituteof KeyLaboratoD，of Gro诵ng Hyb谢Materials， 266071) QingdaoUniversity，Qingdao Abltr嗣lctSijver are method withaco辩 nanoparticlespreparedbyreduc抽g compositenanoparticles Ag@Si()z shellstructureare amodifiedStObermethodin and preparedby et‰lt-butanol showthat Si02一coveredsilver as beobtainedinethanol，butnot regular nanoparticles(briefly-markedAg@Si()z)call int—butanoLTheXRDmeasurI叮nentindicatesthatthesilvermnoDarticlesareface—centeredcubic(fcc)structurewith and measurementshowsthatthe isestablishedbet、^雠ncore SiQshelL highcrystallinity．XPS complexbonding Ag Theshellthicknessofsilver anotablerotein U、厂_visible mnopanicles spectralproperties． spectroscopy㈣rds