合成温度和配料组成对粉煤灰制备β-Sialon基复合材料的影响.pdfVIP

Available online at www.sciencedirect.∞m _- Transactions of 黯 .~; ScienceDirect Nonferrous Metals Society of China Trans. Nonferrous Met. Soc. China 22(2012) 129- 133 www.tnmsc.ιn Effects of synthesis temperature and raw materials composition on preparation ofß-Sialon based composites from fly ash MA Bei-yue, LI Ying, YAN Chen, DlNG Yu-shi School ofMaterials and Metallurgy, Northeastem University, Shenyang 110819, China Received 30 October 2010; accepted 27 May 2011 Abstract: ß-Sialon based composites w臼.e successfully prepared 仕om fly ash and carbon black under nitrogen atmosphere by carbothermal reduction-ni位idation process. Effects of heating temperature and raw materials composition on synthesis process were investigated., and the formation process of the composites was also discussed. The phase composition and microstructure of the composites were characterized by X-ray di债action and scanning electronic microscopy. The results show that increasing heating temperature or mass ratio of carbon black to fly ash can promote the formation of ß-Sialon. The ß-Sialon based composites can be synthesized at 1723 K for 6 h while heating the sample with mass ratio of carbon black to fly ash of 0.56. The as-received ß-Sialon in th