拟再审修改稿 200710034 碱熔融法合成naa和nax型粉煤灰沸石的 .doc

拟再审修改稿 200710034NaA和NaX型粉煤灰沸石的品质表征( 王春峰，李健生，韩卫清，孙秀云，王连军 （210094）NaA和NaX型沸石，并对产物的结构、性能和应用指标进行了详细表征。经X射线衍射和IR光谱分析，表明合成产物是无杂晶生成的NaA和NaX型沸石相；在扫描电镜观察下，产物分别具有NaA和NaX型沸石的立方体和八面体晶体骨架结构。DTA分析表明了合成产物中沸石水的存在，且产物热稳定性较好。通过对比，粉煤灰合成的NaA和NaX型沸石的比表面积达到了相应商品沸石的66.9%和83.6%；孔容为41.1%和70.2%；阳离子交换容量（CEC, Cation Exchange Capacity）82.93%和84.31%。通过比较化学组成表明，大规模应用合成产物不会对环境造成危害。 关 键 词：粉煤灰；NaA和NaX型沸石；碱熔融法；表征 中图分类号： 文献标识码 A 文章编号： Property characterization of zeolites NaA and NaX from fly ash using alkaline fusion method Wang Chunfeng, Li Jiansheng, Han Weiqing, SunXiuyun, Wang Lianjun, (School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China) Abstract: Single-phase zeolites NaA and NaX were synthesized from fly ash using alkaline fusion method during hydrothermal reaction. The products were characterized detailedly from structure, performance and application index. Analysis of XRD and IR spectra shows that the products are confirmed by zeolites NaA and NaX without the presence of other phases, respectively. SEM observation illustrates that the products are cubic and octahedral zeolitic particles, respectively. DTA curves indicate the presence of zeolitic water in the products and the products have better stabilization. The surface area, pore volume and CEC (CEC, Cation exchange capacity) values of the synthetic zeolites NaA and NaX from fly ash reach to 66.9% and 83.6%; 41.1% and 70.2%; 82.93% and 84.31% when compare with these of the corresponding commercial zeolites, respectively. The elemental composition shows that the products do not pose any serious threat to the environment when compare with commercial zeolites. Key words: fly ash; zeolites NaA and NaX; alkaline fusion method; characterization 粉煤灰是以煤为燃料火力发电厂排放的固体废弃物，除部分用作水泥、混凝土等建材原料外，大多作露天堆放，这造成了大气颗粒物污染等环境问题。因此粉煤灰的处置和再利用问题一直为人们所关注。 沸石是一种重要的无机微孔材料，在许多工业过程包括催化、吸附和离子交换等有广泛的应用。沸石生产一般采用、铝硅酸钠盐合成,其原料的来源较少,价格较贵。[1]，以铝硅酸盐非晶形玻璃状物质（占60%～80%Holler和Wirsching[2]首次采用传统水热法由粉煤灰合成沸石以来，新的合成技