煤、顶底板破碎岩体对CO2气体吸附特性的实验研究.pdfVIP

摘 要 前人对煤吸附 CO2 气体已进行了大量的研究，但其吸附机理尚未完全取得一致 认识。此外，近一两年才兴起页岩对 CO2 气体吸附的研究，可见页岩的吸附理论仍 处于起步阶段。本文在前人研究的基础上，将对采空区中的煤和页岩吸附 CO2 气体 的特性做进一步的研究。 首先，从理论上研究了煤、页岩对 CO2 气体的吸附及其影响吸附能力的主要因 素；其次，对南阳坡、陈四楼和红庙三个煤矿的煤、页岩进行了工业分析；再次， 采用 WY-98A 型吸附常数测定仪对煤、页岩吸附 CO2 气体的现象进行了较系统地研 究，通过大量实验数据，得出了不同煤及页岩对 CO2 气体的吸附特性，并对吸附特 性的变化规律进行了分析，采用了几种常用吸附模型对煤、页岩吸附 CO2 气体进行 模拟，优选出更适合用于描述煤、页岩吸附 CO2 气体的模型；然后通过对煤、页岩 表面自由能的计算，分别比较了煤、页岩单位面积吸附量的大小；最后，分别计算 了南阳坡、陈四楼和红庙三个矿区 1t 煤及 1t 页岩可吸附 CO2 的量。研究结果对防 治井下采空区煤炭自燃及 CO2 封存具有重要的指导意义。 关键词：煤；页岩；二氧化碳；吸附特性；吸附模型；吸附等温线 - I - Abstract The adsorption mechanism of coal to CO2 has not yet been fully consistent although lot of research work has been done by many researchers. In addition, the arisen study on the sorption of shale to CO2 in the last one or two years proved the shale’s sorption theory is still in the initial stage. The sorption properties of both coal and shale to CO in goaf were carried out in this paper based on the previous research. 2 First, the main influence factors of the CO absorption capacity was studied from 2 theories. Secondly, the coal shale of Nanyangpo, Chensilou and Hongmiao mining areas were analyzed. Second, the absorption of CO2 gas phenomena was studied using WY-98A absorption determinator systematically. The absorption effect on the imitated coal and shale samples were evaluated, and a suitable model to describe the absorption of CO of coal and shale are selected for optimization. Again, the coal samples’ size of 2 absorption quantity per unit area with shale samples are compared according to the coal and shale samples’ surface free energy computing resu