FCC汽油中硫醚硫的测定--四乙酸铅电位滴定法.pdfVIP

Chin凹e J, Chem, Eng 12 (3) 448 … 450 (2004) RESEARCH NOTES Determination of Sulfides in FCC Gasoline by U sing the Potentiometric Titration of Lead Tetraacetate* LUO Liwen(罗立大) and XIA Daohon臣(更道宏) College of Che回emist剖也tr叩γand CαE田 Pet盯rο01.刨um(但E础t 巳hina叫)， Döngy;ng 25706 1, China Abstract Compared with conventiona. 1method of violet 叩ectrum， determination of the content of sulfì. d回 influîd c~tÇt.lytÍç çracking: (FCC) g辅。line by usíng the potentiometric tit阳.tiòn òf lea.d tetr国回国te h田间.me advant吨回 such 阳 clear potentiometríc a.brupt cha.nge a.t the stöichiòmetric poinh stable potentiometric 陆lue， exa.ct and credible results , a.ndωmple op旧时灿n. The content of sulfides ìn FCC g础。line of Shenghua. refinery 恼。 136现 by this method. The standa.rd deviatíon 也hout this method is less tha.n 0.01% 时ld the relatìve sta.nd a.rd devía.tion is less 也ha.n 2.42% K‘~ywords sul筑de，感酬:line， lead tetra.açeta.te , potentiometric titra.tion 1 INTRODUCTION chromatograph , which h制 some trivial steps. There Th. sulfur content is an important index in is an unclear potentiometric abrupt change at the petroleum products particularly in ga.s oline. Sulfur stoichiometric point[7]. In the ultraviolet spectrum compounds in petroleum will be oxìdized into 50. method , the stÙ.fides 时e transformed into a complex 飞~hen it is burnt a.s fuel , which causes serious envi- in the presence of iodine and isooctane solvent , with ronmental pollution. In recent years , allowable sul- many interference factors and unstable reading value. fur levels in transportation fuels have been drastically There are some excellent results for d