一步法制备纳米铂石墨烯及电催化甲醇的交流阻抗和扩散系数测定.pdfVIP

无机化学学报 第 32 卷第 7 期 Vol.32 No.7 2016 年 7 月 CHINESE JOURNAL OF INORGANIC CHEMISTRY 1170-1 176 -步法制备纳米铀/石墨烯及电催化甲醇的交流阻抗和扩散系数测定 刘文超 吕桂琴* (北京理工大学化学学院，北京 l 旺)()81) 摘要:采用绿色还原剂抗坏血酸.一步法制备纳米铅/石墨烯。 对其进行 X 射线衍射(XRD) 、扫描电子显微镜(SE町、 透射电子显 微镜σEM)形貌结构表征，锦纳米粒子均匀分散于纳米石墨烯片层栩皱间，有效减少了团聚现象。 运用循环伏安法(CV)和计时电 流法(CA)研究纳米钳/石墨烯对甲静电催化氧化活性和稳定性，通过交流阻抗但盼定量测定，发现铅/石墨烯比锦具有更优异的 2 电荷传输性能，电荷转移阻抗下降了 34.8%。 计时电量法(CC)测定得到甲醉在锦/石墨烯电极的表面扩做系数为 1.42xlO-9 cm , S-I 。 与锦纳米拉子相比，纳米销/石墨烯对甲醇电催化氧化具有更高的活性和稳定性，显著提高电极催化活性表面积和电荷传输 及转移性能。 关键词:销/石墨矫;电催化;交流阻抗;计时电盘 中图分类号: 0613.71; 0614.826; 0643.361 文献标i只码:A 文章编号: 1 ∞1 -4861 (2016)07-川70-07 DOI: 1O.1 18621CJIC.2016. 149 Nano-PtlGraphene: One Step Synthesis and Characterization by AC Impedance and Diffusion C oefficient for E lectrocataly sis of Methanol LIU Wen-Chao LOGui-Qin* (Schωl 01 Chemistry, Beij吨ln.stitute 01 Tech1Wwgy, Beiji暗 lαlO81， ChiTUl) Ab stract: Nano-Ptlgraphene was prepared by adopting ascorbic acid as environmentally friendly reductant in one毛tep process . The morphology and s位ucture of the products were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and transmission electron microscope σEM). The results indicate that Pt nanoparticles are well dispersed in the wrinkled graphene nanosheets , which effecti vely prevents the a部regat ion of Pt nanoparticles, The electrocatalytic activity and stahility of the catalysts for methanol oxidation were investigated by cyclic voltammetry (CV) and