生物乙醇副产物-聚乳酸复合材料的性能研究.pdfVIP

第 41 卷第 5 期 化工新型材料 Vo l. 41 No.5 2013 年 5 月 NEW CHEMICAL MATERIALS • 71 • 生物乙醇副产物-聚乳酸复合材料的性能研究 张明明1 刘晓欢1 储富祥2 王春鹏1，2 金立维1.2 赞 (1.中国林业科学研究院林产化学工业研究所;生物质化学利用国家工程实验室;国家林业局林产 化学工程重点开放性实验室;江苏省生物质能源与材料重点实验室，南京 210042; 2. 中国林业科学研究院林业新技术研究所，北京 10009 1) 摘 要 采用熔融挤出工艺制备了聚乳酸(PLA)-生物乙醇副产物(BEB)共混材料。考察了 BEB 及3 种相容剂对材 料力学性能的影响，并通过接触角测量、热重分析(TGA)和扫描电镜(SEM)等手段对材料的性能及微观形貌进行了分析 表征。结果表明:随着 BEB 含量的升高，共混材料的力学性能逐步降低，而相容剂的加入则能在一定程度上提高共混材 料的拉伸强度，同时使共混物的表面自由能降低到纯聚乳酸的水平。与简单共混物相比，增容材料的热稳定性得到了加 强，其玻鸦化转变的温度区间也变窄。 关键词 生物乙醇副产物，聚乳酸，熔融挤出，共混材料 Study 00 properties of bio-ethaool byproduct-polylactide composite 1 1 2 1 Zhang Mingming Liu Xiaohuan Chu Fuxiang Wang Chunpeng ,2 Jin Liweil ,2 (1. Institute of Chemical Industry of Forestry Products ,CAF; National Engineering Lab. for Biomass Chemical Utilization; Key and Lab. on Forest Chemical Engineering ,SFA; Key Lab. of Biomass Energy and Material ,Nanjing 210042; 2. Institute of Forest New Technology ,CAF ,Beijing 10009 1) Abstract The blend composite materials of bi命ethanol byproduct-polylactide (PLA) were produced by a melting extrusion process. Effects of bi命ethanol byproduct(BEB) and three different kinds of compatibilizer on mechanical proper ties of the composites were investigated. Properties and morphology of the composites were studied by measurement of con- tact angle ,thermogravimetric analysis(TGA) and scanning electron microscope(SEM) and so 0且 The research showed that with increase of contents of bio-ethanol byproduct , the mechanical properties was