使用顶空单滴微萃取法测定纺织品中甲醛.pdfVIP

每岳强拉幸 第 43 卷第4 期 2015 年 4 月 Cotton Textile Technology 29 1 使用顶空单滴徽萃取法测定纺织晶中甲醒 顾虎秦鑫沈鉴 (杭州市质量技术监督检测院，浙江杭州，310019) 摘要: 介绍基于顶空羊滴微萃取结合高效液相色谱法测定纺织品中甲醒的新方法。对萃取剂(包括乙 航丙嗣浓度、pH 值、乙酸钱浓度和有机溶剂组成)、萃取衍生温度、NaCl 浓度和萃取时间进行了优选。采用顶空 单滴微萃取结合高效液相色谱法测定了纺织品中甲酶，并与紫外-可见光分光光皮法和高效液相色谱法进行了 对比。结果表明:在萃驭异IJ pH=5、含1. 5%(V!V) 乙航丙翻和 3 mol/ L 乙酸馁的甘油-DMF 溶液、萃取温度 70C 、卒取时间 2 min、 NaCl 浓度 25%(m!V) 的条件下，顶空单滴很萃取结合高效液相色谱法的相对标准偏差 (n=6) 小子 7% ，检测限〈以 S/N=3)和定量限(以 S!N=10) 分别为 1.2 mg/kg 和 3.5 mg/kg。认为 2 新方法可 用于纺织品中甲隆含量的测定。 关键询: 顶空单滴微萃取;甲路;纺织品;高效液相色谱;萃取工艺;测试精度 中固分类号:TS107 文献标志码:B 文章编号:1001-7415(2015)04-0029-05 Formaldehyde Test of Textile with Method of Headspace Solvent Microextraction Gu Hu Qin Xin Shen Jian (Hangzhou Quality and Technology Supervision Detection 1nstitute ,Zhejiang Hangzhou ,310019) Abstract New method testing formaldehyde in textile based on headspace single drop microextraction com bination with high efficiency liquid chromatography was introduced. Extraction agents extraction derived tempera- ture ,NaCl concentration and extraction time were optimized. Formaldehyde was tested by method of headspace single drop microextraction combination with high efficiency liquid chromatography. Results were compared with methods of ultraviolet-visible spectrophotometry and high efficiency liquid ehromatography. The result shows that when extraction pH value is 5 ,glycerinum-DMF solution contains is 1. 5 % acetylacetone and 3 mo l!L amm口nlum acetate ,extraction temperature is 70 C , extraction time is 2 min and NaCl concentration is 25% , the relative standard deviation is less than 7%.ln addition ,test l