全自动石墨加热消解-FAAS法测定土壤中的铅.pdfVIP

安徽农业科学，Journal of Anhui Agri. Sci. 2015 ,43(36) :31 -32 责任编缉刘月精责任校对况玲玲 全自动石墨加热消解-FAAS 法测定土壤中的铅 张秀丰1 ，霍硕莉2 ，付艳梅I (l 衡水出入境检验检疫局，河北衡水旧棚;2 河北省衡水市衡水学院，河北衡水朋刷) 摘要 [目的]为了建立测定土壤中的铅含量的全自动石墨消解-FAAS 法。[方法]利用盐酸-硝酸-氢氟酸-高氯酸作为消解液，经 全自动石墨加热消解，Kl-MIBK 萃取，采用火焰原子吸收光谱法测定土壤样品中的铅含量。[结果]铅(0.2 -1. 0 mglL) 的吸光度与浓度 线性关系较好， r 为 0.999 5 ，检出限为 0.18 mglkg ，回收率为 97.8% -103.2% ，此SD 为 2.687毛 -3.887岛。[结论]该方法检测l 效率高，操 作简便，准确性好，是测定土壤中铅含量的理想方法。 关键词 石墨加热消解;土壤;铅 中图分类号 S 151. 9 丁 文献标识码 A 文章编号 0517 -6611 (2015 )36 -031 -02 Deten回nation of Lead in Soi1 with Automatic Graphite Digestion Instrument by FAAS z ZHANG Xiu-feng , ZHAI Shuo-Ii , FU Yan-mei (1. Hengshui Entry-Exit Inspection and Quarantine Bureau , Hengshui , Hebei 053α)(); 2. Hengshui University , Hengshui , Hebei 053创则) Abstract [ Objeclive]ηle research aimed 10 eslablish a melhod wilh aulomalic graphile digeslion inslrument by using flame alomic absorp- lion speclropholometry ( FAAS )如 the delerminalion of lead in soil. [Melhod] Using hydrochloric acid-nilric acid忖drofluoric acid-perchloric acid as remove fluid , Ihe soil samples were digesled by automalic graphile digeslion inslrumenl , Ihen lhe lead conlenl in Ihe soil was delecled by KI-MIBK extraction aulomatic graphite digestion instrument. [Result] The linear relationship between values of absorbance and mass con- centration of lead was kept in ranges of O. 2 - 1. 0 mglL , amd r was 0.999 5 with the detection limit of 0.18 mglkg. 叽le recoveηrate ob- tained by standard addition method was in Ihe range of 97.8% -103.2% with RSD of 2. 689毛 -3.88%. [Conclusion]ηle method is sim- ple , rapid and accurale , which is an ideal method for the determination of lead contenls in the soil. Key words Automatic graphite digestion; Soil; Lead 各种酸用量