关于水样中总氰化物分析结果测定的思考.pdfVIP

安徽农业科学，Journal of Anhui Agri. Sci. 2013 ,41 (36) : 14011 , 14062 责任编辑黄小燕责任校对李洪 关于水样中总氧化物分析结果测定的思考 李金，陈志宁，谢文理 (江苏省常州市环境监测中心，江苏常州川剧) 摘要 [目的]研究水样中总氯化物测定时的注意事项。[方法]通过对氯化物的特性、氯化匆储备溶液浓度标定、氯牍T、异烟酸的性质 以及显色温度等因素的探讨，分析影响实验结果的因素，总结出实验时注意事项。[结果]在测定总融化物的过程中，实验试剂和操作因 素对测定结果影响较大。操作时必须认真、细心，尽量避免人为影响;在标定溶液时应注意滴定终点，增加平行样个数，防止偏差过大; 在试剂配制时，尽量注意试剂浓度的准确。[结论]该研究为水环境的监测提供理论依据。 关键词 总氯化物;异烟酸-.比哇琳嗣法;现IJ 定结果;影响因素 中图分类号 S 181. 3 文献标识码 A 文章编号 0517 -6611 (2013 )36 -14011 -01 Ret1ectioßS on the Analy由ResuI也 of Dete口曲回也Jg T侃aI Cyanide in Water Samples LI Jin et aI ( Chang烛。u Environmental Monitoring Center ,Changzhou ,Jiangsu 213∞1 ) Abstract [ Ohjective Jηle research aimed to study the considerations of total cyanide determination in water samples. [MethodJ Through inves- tigating such as characteristics of cyanide , calihrating potassium cyanide stock solution concentration , the nature of chloramines T , the nature of isonicotinic acid , chromogenic temperature ,the factor百 of affecting the experimental results were analyzed ,and the considerations through experi- ment was summarized. [ Result J In the process of determinating total cyanide , the infl阳lce of laboratory reagents and operational factors on the determine results were bigger. Operation must be carefully ,try one s best 10 avoid artificial effect. When calibraling a solution ,it should be noted titration endpoint , increasing the number of parallel samples , 10 prevent excessive deviation. In the reagenl prep缸ation ，盯 10 pay attention to the exact concentralion of Ihe reagent. [Conclusion] The study provides the Iheoretical basis for Ihe monitoring of the water environment. Key words Total cyanide; lsonicotinic acid-Pyrazolone melhod; Determine resull; Influencing factors EDTA 榕液加入蒸馆瓶内。迅速加入 10 时磷酸，当样品碱 氨化物是一种毒性很强的污染物，对人体的毒性主要是 与高铁细胞色素氧化酶结合，生